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zvonat [6]
3 years ago
9

According to Charles law when the temperature of a gas at constant pressure is increased it

Chemistry
1 answer:
Anestetic [448]3 years ago
5 0


According Charles law, when the temperature of a gas at constant pressure is increased, the volume of the gas increases.  The law states that for a mixed mass of a gas at constant pressure, the volume is directly proportional to the Kelvin temperature.

That is to say that if for example you double the Kelvin temperature from, say 400K to 600k, at  a constant pressure, the volume of a mixed mass of the gas will double as well.

Charles studied the compressibility of gases nearly 100 years  after  Boyle. In his experiments, he noted that at fixed pressure, the volume of a gas is proportional to the temperature of the gas.

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What is the molar mass of a substance?
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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are
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<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

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