Answer: Reaction (4)
Conservation of charge means net charge of the system is same. If in a chemical equation, charge on the reactant side is same as that on the product side, it shows the conservation of charge.
The given reactions are as follows:




In reaction (1), charge on reactant side is +1 and that on product side is +2 thus, it does not show conservation of charge.
In reaction (2), charge on reactant side is +2 and that on product side is +4 thus, it does not show conservation of charge.
In reaction (3), charge on reactant side is -1 and that on product side is -2 thus, it does not show conservation of charge.
In reaction (4), charge on reactant side is -2 and on product side is also -2 thus, it shows conservation of charge.
Therefore, reaction (4) is correct answer.