Answer:
51 J
Explanation:
The air inside a bicycle tire pump has 27 joules of heat conducted away. By convention, when heat is released, it takes the negative sign, so Q = -27 J.
77.9 joules of work done are being done on the air inside a bicycle tire pump. By convention, when work is being done on the system, it takes the positive sign, so W = 77.9 J
We can calculate the change in the internal energy (ΔU) using the following expression.
ΔU = Q + W
ΔU = (-27 J) + 77.9 J
ΔU = 51 J
<u>Answer:</u> The 
for HCN (g) in the reaction is 135.1 kJ/mol.
<u>Explanation:</u>
Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. The equation used to calculate enthalpy change is of a reaction is:
![\Delta H_{rxn}=\sum [n\times \Delta H_f(product)]-\sum [n\times \Delta H_f(reactant)]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H_f%28product%29%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H_f%28reactant%29%5D)
For the given chemical reaction:
The equation for the enthalpy change of the above reaction is:
![\Delta H_{rxn}=[(2\times \Delta H_f_{(HCN)})+(6\times \Delta H_f_{(H_2O)})]-[(2\times \Delta H_f_{(NH_3)})+(3\times \Delta H_f_{(O_2)})+(2\times \Delta H_f_{(CH_4)})]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28HCN%29%7D%29%2B%286%5Ctimes%20%5CDelta%20H_f_%7B%28H_2O%29%7D%29%5D-%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28NH_3%29%7D%29%2B%283%5Ctimes%20%5CDelta%20H_f_%7B%28O_2%29%7D%29%2B%282%5Ctimes%20%5CDelta%20H_f_%7B%28CH_4%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![-870.8=[(2\times \Delta H_f_{(HCN)})+(6\times (-241.8))]-[(2\times (-80.3))+(3\times (0))+(2\times (-74.6))]\\\\\Delta H_f_{(HCN)}=135.1kJ](https://tex.z-dn.net/?f=-870.8%3D%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28HCN%29%7D%29%2B%286%5Ctimes%20%28-241.8%29%29%5D-%5B%282%5Ctimes%20%28-80.3%29%29%2B%283%5Ctimes%20%280%29%29%2B%282%5Ctimes%20%28-74.6%29%29%5D%5C%5C%5C%5C%5CDelta%20H_f_%7B%28HCN%29%7D%3D135.1kJ)
Hence, the for HCN (g) in the reaction is 135.1 kJ/mol.
The true answer is: It's conserved because the total number of H atoms on each side is 12.
the first two answer is wrong because it's conserved not as mentioned, It's not conserved.
and the last one also wrong because the total number of O atoms are equal at the two sides but not equal 2.
