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stepan [7]
3 years ago
14

Despite not knowing mechanistic details of the adsorption of water onto silica gel, from the information provided, you should be

able to make an educated guess about the thermodynamic characteristics of the process. Predict the signs of ΔG, ΔH, and ΔS.
Chemistry
1 answer:
navik [9.2K]3 years ago
8 0

Answer:

G<0, spontanteous

H<0, from equation

S>0, gas to solid

Explanation:

The small bags of silica gel you often see in a new shoe box are placed there to control humidity. Despite its name, silica gel is a solid. It is a chemically inert, highly porous, amorphous form of SiO2. Water vapor readily adsorbs onto the surface of silica gel, so it acts as a desiccant. Despite not knowing mechanistic details of the adsorption of water onto silica gel, from the information provided, you should be able to make an educated guess about the thermodynamic characteristics of the process. Predict the signs of ΔG, ΔH, and ΔS.

G<0, spontanteous

H<0, from equation

S>0, gas to solid

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Answer: 20.775 g S

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4 0
2 years ago
At 2°C, the vapor pressure of pure water is 23.76 mmHg and that of a certain seawater sample is 23.09 mmHg. Assuming that seawat
wariber [46]

Answer:

0.808  M

Explanation:

Using Raoult's Law

\frac{P_s}{Pi}= x_i

where:

P_s = vapor pressure of sea water( solution) = 23.09 mmHg

P_i = vapor pressure of pure water (solute) = 23.76 mmHg

x_i = mole fraction of water

∴

\frac{23.09}{23.76}= x_i

x_i = 0.9718

x_i+x_2=1

x_2 = 1- x_i

x_2 = 1- 0.9718

x_2 = 0.0282

x_i = \frac{n_i}{n_i+n_2}  ------ equation (1)

x_2 = \frac{n_2}{n_i+n_2}  ------ equation (2)

where; (n_2) = number of moles of sea water

(n_i) = number of moles of pure water

equating above equation 1 and 2; we have :

\frac{n_2}{n_i}= \frac{0.0282}{0.9178}

= 0.02901

NOW, Molarity =  \frac{moles of sea water}{mass of pure water }*1000

= \frac{0.02901}{18}*1000

= 0.001616*1000

= 1.616 M

As we assume that the sea water contains only NaCl, if NaCl dissociates to Na⁺ and Cl⁻; we have \frac{1.616}{2} =0.808 M

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