Answer:
Hexane should be used first.
Explanation:
Chromatography is a method of separating the constituents of a mixture by taking advantage of their different rates of movement in a solvent over an adsorbent medium. Chromatography is a means of separation and analysis that utilises fractional separation. It is based on the principle that if a fluid containing a number of substances is allowed to pass though an adsorbent medium, the different substances in the fluid may travel at different rates and be separated.
The rate of movement depends on the relative affinities of the constituents for the solvent and adsorbent medium. i.e solutes which are weakly adsorbed by the adsorbent medium are easily redissolved by the ascending solvent and quickly travel up the adsorbent medium. In addition to that , solutes which are very soluble in the solvent move up at a faster rate than those which are not soluble.
In column Chromatography;
A non-polar solvent should be initiated and applied first. This is because , in a column chromatography, a non-polar compound will be removed at first then later polar compound.
Assuming a polar compound is used first, the polar compounds will be removed alongside with all the non-polar compounds.
From the two Compounds given;
We know that :
Hexane is a non-polar compound and Methylene chloride is a polar compound. As such, Hexane should be used first.
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Since volume and temperature are constant, this means that pressure and <u>number of moles</u> are <u>directly </u>proportional. the sample with the largest <u>number of moles</u> will have the <u>high </u>pressure.
Since, the ideal gas equation is also called ideal gas law. So, according to ideal gas equations,
PV = nRT
- P is pressure of the sample
- T is temperature
- V is volume
- n is the number of moles
- R is universal gas constant
At constant volume and temperature the equation become ,
P ∝ nR
since, R is also constant. So, conclusion of the final equation is
P ∝ n
The number of moles and pressure of the sample is directly proportion. So, on increasing number of moles in the sample , pressure of the sample also increases.
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The law of definite proportions agrees with Dalton atomic theory.
What is Dalton atomic theory?
It state that all matters is made of very tiny particles called atom. atoms are individual particles which can not be created or be destroyed in a chemical reactions. Atoms of given elements are identical in mass and chemical properties. Atoms of
different elements have different masses and chemical properties.
The law of definite proportions also known as proust's law ,state that a chemical compound contain the same proportion of elements by mass.this law is one of the stoichiometry .
Thus ,
This is the reason why it is agrees with dalton atomic theory.
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