How many atoms are accommodated by the available orbitals for Ne?

A solution was prepared by dissolving 0.800 g of sulfur S8, in 100.0 g of acetic acid, HC2H3O2. Calculate the freezing point and

Romashka [77]

Answer: The freezing point of solution is 16.5°C and the boiling point of solution is 118.2°C

Explanation:

To calculate the molality of solution, we use the equation:

$Molality=\frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ in grams}}$

Where,

$m_{solute}$ = Given mass of solute $(S_8)$ = 0.800 g

$M_{solute}$ = Molar mass of solute $(S-8)$ = 256.52 g/mol

$W_{solvent}$ = Mass of solvent (acetic acid) = 100.0 g

Putting values in above equation, we get:

$\text{Molality of solution}=\frac{0.800\times 1000}{256.52\times 100.0}\\\\\text{Molality of solution}=0.0312m$

Calculation for freezing point of solution:

Depression in freezing point is defined as the difference in the freezing point of water and freezing point of solution.

$\Delta T_f=\text{freezing point of acetic acid}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

or,

$\text{Freezing point of acetic acid}-\text{Freezing point of solution}=iK_fm$

where,

Freezing point of acetic acid = 16.6°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal freezing point depression constant = 3.59°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$16.6^oC-\text{freezing point of solution}=1\times 3.59^oC/m\times 0.0312m\\\\\text{Freezing point of solution}=16.5^oC$

Hence, the freezing point of solution is 16.5°C

Calculation for boiling point of solution:

Elevation in boiling point is defined as the difference in the boiling point of solution and freezing point of pure solution.

The equation used to calculate elevation in boiling point follows:

$\Delta T_b=\text{Boiling point of solution}-\text{Boiling point of acetic acid}$

To calculate the elevation in boiling point, we use the equation:

$\Delta T_b=iK_bm$

or,

$\text{Boiling point of solution}-\text{Boiling point of acetic acid}=iK_fm$

where,

Boiling point of acetic acid = 118.1°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal boiling point elevation constant = 3.08°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$\text{Boiling point of solution}-118.1^oC=1\times 3.08^oC/m\times 0.0312m\\\\\text{Boiling point of solution}=118.2^oC$

Hence, the boiling point of solution is 118.2°C

8 0

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What are the molality and mole fraction of solute in a 22.3 percent by mass aqueous solution of formic acid (HCOOH)?

Vanyuwa [196]

Answer:

Mole fraction for solute = 0.1, or 10%

Molality = 6.24 mol/kg

Explanation:

22.3% by mass → In 100 g of solution, we have 22.3 g of HCOOH

Mass of solution = 100 g

Mass of solute = 22.3 g

Mass of solvent = 100 g - 22.3g = 77.7 g

Let's convert the mass to moles

22.3 g . 1mol/ 46 g = 0.485 moles

77.7 g. 1mol / 18 g = 4.32 moles

Total moles = 4.32 moles + 0.485 moles = 4.805 moles

Xm for solute = 0.485 / 4.805 = 0.100 → 10%

Molality → mol/ kg → we convert the mass of solvent to kg

77.7 g. 1 kg / 1000g = 0.0777 kg

0.485 mol / 0.0777 kg = 6.24 m

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