Answer:
A. The equilibrium will shift to the right.
Explanation:
For Le Chatêlier's principle, when there is a disturb in an equilibrium reaction, the equilibrium shift to reduce the effects of the disturb, and then a new equilibrium is formed.
So, for the reaction given:
2SO₂(g) + O₂(g) ⇄ 2SO₃(g) + heat
If more sulfur dioxide, SO₂, is added, to reduce the disturb, the SO₂ must be consumed, so the equilibrium will shift for the right.
The Keq remains constant. The equilibrium constant only changes if there is a change in temperature.