The heat released : -110560.632 J
<h3>Further explanation</h3>
Heat can be calculated using the formula:
Q = mc∆T
Q = heat, J
m = mass, g
c = specific heat, joules / g ° C
∆T = temperature difference, ° C / K
<h3>Known</h3>
m =465 g
c water = 4.186 J/gram °C
∆T = temperature difference = 18.2 - 75 = - 56.8 °C
Then the heat :

Chiral center is the center where all the attached substituents are different. For example, a carbon is said to be chiral carbon if it is attached to four different substituents.
The structure of threonine is attached here.
The marked carbons are chiral carbons because they have all the 4 different substituents.
One mole of an ideal gas will occupy 22.4 liters of volume at STP.
If the only thing that changes is the pressure from 1.00 atm to 2.00 atm, then we know the initial volume, initial pressure, and final pressure. We can use Boyle's law.
Boyle's law: (initial pressure)*(initial volume) = (final pressure)*(final volume)
fill in the knowns
(1.00 atm)*(22.4 liters) = (2.00 atm)(final volume)
divide both sides by 2.00 atm
11.2 liters = final volume