Answer:
According to Hund's rule and the Aufbau principle in which the orbitals must be filled with electrons, they are not strictly applied in the real universe, because the intermediate and electron-filled atomic orbitals are very stable . Because there are four d-orbitals in universe L, a typical half-full configuration will be xd4 and its full configuration will be xd8, where x is the primary orbital for any specific element. Here is an example:
Vahadium ₂₃V
in real universe: [Ar]₈ 3d³4s²
in universe L: [Ar]₁₈ 3d⁴4s¹
Chromium
in real universe: [Ar]₈ 3d⁵4s¹
in universe L: [Ar]₁₈ 3d⁴4s²
Explanation:
Explanation:
The given reaction equation will be as follows.
![[FeSCN^{2+}] \rightleftharpoons [Fe^{3+}] + [SCN^{-}]](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D%20%5Crightleftharpoons%20%5BFe%5E%7B3%2B%7D%5D%20%2B%20%5BSCN%5E%7B-%7D%5D)
Let is assume that at equilibrium the concentrations of given species are as follows.
![[Fe^{3+}] = 8.17 \times 10^{-3}](https://tex.z-dn.net/?f=%5BFe%5E%7B3%2B%7D%5D%20%3D%208.17%20%5Ctimes%2010%5E%7B-3%7D)
M
![[SCN^{-}] = 8.60 \times 10^{-3}](https://tex.z-dn.net/?f=%5BSCN%5E%7B-%7D%5D%20%3D%208.60%20%5Ctimes%2010%5E%7B-3%7D)
M
![[FeSCN^{2+}] = 6.25 \times 10^{-2}](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D%20%3D%206.25%20%5Ctimes%2010%5E%7B-2%7D)
M
Now, first calculate the value of 
as follows.
![K_{eq} = \frac{[Fe^{3+}][SCN^{-}]}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BFe%5E%7B3%2B%7D%5D%5BSCN%5E%7B-%7D%5D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
= 
= 
Now, according to the concentration values at the re-established equilibrium the value for ![[FeSCN^{2+}]](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D)
will be calculated as follows.
![11.24 \times 10^{-4} = \frac{8.12 \times 10^{-3} \times 7.84 \times 10^{-3}}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=11.24%20%5Ctimes%2010%5E%7B-4%7D%20%3D%20%5Cfrac%7B8.12%20%5Ctimes%2010%5E%7B-3%7D%20%5Ctimes%207.84%20%5Ctimes%2010%5E%7B-3%7D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
![[FeSCN^{2+}] = 5.66 \times 10^{-2}](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D%20%3D%205.66%20%5Ctimes%2010%5E%7B-2%7D)
M
Thus, we can conclude that the concentration of in the new equilibrium mixture is 
M.
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Answer:
yes solution is always a mixture but not all mixtures are solution
Explanation:
A solution.is a homogeneous mixture of substance that have uniform composition throughout
And a mixture hVe twoo or more substances that are not chemically.combine
