The first two ionization energies of nickel.

1 answer:

7 0

The first two ionization energy of nickel are expressed as:
Ni(g) = Ni^+(g) + e^- Ni^+(g) = Ni^2+(g) + e^-
IOnization energy os the energy that is neccessary in order to remove one mole of electrons from an atom.
Hope this helps.

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Dissolution of KOH, ΔHsoln:

swat32

Using Hess's law we found:

1) By adding reaction 10.2 with the reverse of reaction 10.1 we get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq) ΔH (10.3)

2) The ΔHsoln must be subtracted from ΔHneut to get the total change in enthalpy (ΔH).

The reactions of dissolution (10.1) and neutralization (10.2) are:

KOH(s) → KOH(aq) ΔHsoln (10.1)

KOH(s) + HCl(aq) → H₂O(l) + KCl(aq) ΔHneut (10.2)

1) According to Hess's law, the total change in enthalpy of a reaction resulting from differents changes in various reactions can be calculated as the sum of all the enthalpies of all those reactions.

Hence, to get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq) (10.3)

We need to add reaction 10.2 to the reverse of reaction 10.1

KOH(s) + HCl(aq) + KOH(aq) → H₂O(l) + KCl(aq) + KOH(s)

Canceling the KOH(s) from both sides, we get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq) (10.3)

2) The change in enthalpy for reaction 10.3 can be calculated as the sum of the enthalpies ΔHsoln and ΔHneut:

$\Delta H = \Delta H_{soln} + \Delta H_{neut}$