Answer:
Identifying whether or not an element is an ion is a very simple process. Identify the charge of the element. ... The number of electrons is equal to the atomic number minus the charge of the atom. Refer to an element with either a positive or negative charge as an ion.
Answer:
balanced in ACID not BASE
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Answer
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Explanation:
Cr2O7^2-(aq) + Hg(l) ----> Hg^2+(aqH) + Cr^3+(aq)
add H^1+ (acid) to capture the O and make 7 water molecules
Cr2O7^2-(aq) + Hg(l) + H^1+ ----> Hg^2+(aqH) + Cr^3+(aq) + 7H2O
Cr goes from +6 to +3 by gaining 3 e
Hg goes from 0 to +2 by losing 2 e
we need 3 Hg for every 2 Cr
so
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
2 Cr on the right and left
Net 12 positive charges on the right and the left
3 Hg on the right and left
14 H on the right and left
the equation is balanced
we cannot balance the equation in a basic solution with OH^1-
we have plenty of O in the dichromate ion. we need to convert it to water which take free H^1+ from the acid
Answer:
D) the carbon with the low-energy phosphate on it in 1,3 BPG is labeled.
Explanation:
Glycolysis has 2 phase (1) preparatory phase (2) pay-off phase.
<u>(1) Preparatory phase</u>
During preparatory phase glucose is converted into fructose-1,6-bisphosphate. Till this time the carbon numbering remains the same i.e. if we will label carbon at 6th position of glucose, its position will remian the same in fructose-1,6-bisphosphate that means the labeled carbon will still remain at 6th position.
When fructose-1,6-bisphosphate is further catalyzed with the help of enzyme aldolase it is cleaved into two 3 carbon intermediates which are glyceraldehyde 3-phosphate (GAP) and dihyroxyacetone phosphate (DHAP). In this conversion, the first three carbons of fructose-1,6-bisphosphate become carbons of DHAP while the last three carbons of fructose-1,6-bisphosphate will become carbons of GAP. It simply means that GAP will acquire the last carbon of fructose-1,6-bisphosphate which is labeled. Now the last carbon of GAP which has phosphate will be labeled.
<u>(2) Pay-off phase</u>
During this phase, GAP is dehydrogenated into 1,3-bisphosphoglycerate (BPG) with the help of enzyme glyceraldehyde 3-phosphate dehydrogenase. This oxidation is coupled to phosphorylation of C1 of GAP and this is the reason why 1,3-bisphosphoglycerate has phosphates at 2 positions i.e. at position 1 in which phosphate is newly added and position 3rd which already had labeled carbon.
It is pertinent to mention here that<u> BPG has a mixed anhydride and the bond at C1 is a very high energy bond.</u> In the next step, this high energy bond is hydrolyzed into a carboxylic acid with the help of enzyme phosphoglycerate kinase and the final product is 3-phosphoglycerate. Hence, the carbon with low energy phosphate i.e. the carbon at 3rd position remains labeled.
KH₂PO₄ hydrolyzes as;
H₂PO₄⁻ + H₂O ↔ H₃PO₄ + OH⁻
Let x amount of H₂PO₄⁻ has reacted with water then,
Kb₁ = [H₃PO₄][OH⁻] / [H₂PO₄⁻]
[H₂PO₄⁻] = 0.8-x M
Kb₁ = x² / (0.8 - x)
Given Ka₁ = 7.5 x 10⁻³
so Kb₁ = 1 x 10⁻¹⁴ / (7.5 x 10⁻³) = 1.33 x 10⁻¹²
From this information:
1.33 x 10⁻¹² = x² / 0.8
x = [OH⁻] = 1.03 x 10⁻⁶ M
pOH = - log (1.03 x 10⁻⁶) = 5.99
pH = 14 - pOH = 14 - 5.99 = 8.01
