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Sergeeva-Olga [200]
3 years ago
11

Part a the disproportionation of mn2+(aq) to mn(s) and mno2(s) in acid solution at 25 ∘c. calculate δg∘rxn.

Chemistry
1 answer:
ollegr [7]3 years ago
4 0

Answer:

ΔG^{o} = -461198.3 J

Explanation:

Gibbs free energy is defined as the energy associated with a given chemical reaction which can be used to do work. Firstly, we need to figure out the chemical equation for the given problem. For the given problem, the chemical equation is:

Mn^{2+} _{(aq)} + 2e^{-}⇒Mn_{(s)}      E^{o} = -1.18 V

Mn^{2+} _{(aq)} + H_{2}O ⇒MnO_{2(s)} +4H^{+} + 2e^{-}E^{o} = -1.21 V

The addition of the two E^{o} gives the E_{cell} of the equation, i.e. -1.18-1.21 = -2.39 V.

Then, using the equation for ΔG^{o}, we have:

ΔG^{o} = n*F*E^{o} = 2*96485*-2.39 = -461198.3 J

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scZoUnD [109]

Answer:

Explanation:

If the enzyme active site is complementary to the substrate conformation rather than to the transition state, it is unlikely that the reaction will proceed and release a product, because the enzyme-substrate complex will be tightly bound (ΔG will raise).

On the other hand, when the enzyme active site is complementary to the transition state, the substrate will not be tightly bound and will be more prone to be transformed into the product (<u>ΔG will be lowered</u>) and afterward, be released.

The weak interactions (non-covalent bonds) will stabilize the energy of the transition state and reduce its energy, thus lowering the activation energy). If the transition state is stable, it will form more easily and<u> the reaction will be more likely to proceed.</u>

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8 0
3 years ago
Can somebody please help with this question?
Leni [432]
Most of the mass of an atom is located in the (nucleus), and most of the volume is taken up by the (electron clouds).

The ones in the parenthesis are your answers.

Hope this helps!
7 0
3 years ago
Calcium carbonate is often used as an antacid. Your stomach acid is composed of HCl at a pH of 1.5. If you ate toooo much Turkey
stiks02 [169]

<u>Answer:</u> 0.0237 g of calcium carbonate would be required to neutralize the given amount of HCl

<u>Explanation:</u>

pH is defined as the negative logarithm of hydrogen ion concentration present in the solution

pH=-\log [H^+]      .....(1)

Given value of pH = 1.5

Putting values in equation 1:

1.5=-\log[H^+]

[H^+]=10^{(-1.5)}=0.0316M

Molarity is defined as the amount of solute expressed in the number of moles present per liter of solution. The units of molarity are mol/L. The formula used to calculate molarity:

\text{Molarity of solution}=\frac{\text{Number of moles of solute}\times 1000}{\text{Volume of solution (mL)}}       .....(2)

We are given:

Volume of solution = 15.0 mL

Molarity of HCl = 0.0316 M

Putting values in equation 2:

0.0316=\frac{\text{Moles of HCl}\times 1000}{15.0}\\\\\text{Moles of HCl}=\frac{0.0316\times 15.0}{1000}=4.74\times 10^{-4}mol

The chemical equation for the reaction of HCl and calcium carbonate follows:

2HCl+CaCO_3\rightarrow H_2CO_3+CaCl_2

By the stoichiometry of the reaction:

2 moles of HCl reacts with 1 mole of calcium carbonate

So, 4.74\times 10^{-4}mol of HCl will react with = \frac{1}{2}\times 4.74\times 10^{-4}=2.37\times 10^{-4}mol of calcium carbonate

The number of moles is defined as the ratio of the mass of a substance to its molar mass.

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Moles of calcium carbonate = 2.37\times 10^{-4}mol

Molar mass of calcium carbonate = 100.01 g/mol

Putting values in the above equation:

\text{Mass of }CaCO_3=(2.37\times 10^{-4}mol)\times 100.01g/mol\\\\\text{Mass of }CaCO_3=0.0237g

Hence, 0.0237 g of calcium carbonate would be required to neutralize the given amount of HCl

7 0
2 years ago
Extreme temperature changes or increased moisture speed up the weathering rate.
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that is a true statement

6 0
3 years ago
Which Of the following compounds is an electrolyte?
Anettt [7]
Hello,

Here is your answer:

The proper answer to this question is option D "<span>sodium hydroxide".

Here is how:

Sodium Hydroxide its a white substance that is a </span><span>electrolyte.

Your answer is D.

If you need anymore help feel free to ask me!

Hope this helps!</span>
8 0
3 years ago
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