Answer : The final temperature of the metal block is, 
Explanation :

As we know that,

.................(1)
where,
q = heat absorbed or released
= mass of aluminum = 55 g
= mass of water = 0.48 g
= final temperature = ?
= temperature of aluminum = 
= temperature of water = 
= specific heat of aluminum = 
= specific heat of water= 
Now put all the given values in equation (1), we get
![55g\times 0.900J/g^oC\times (T_{final}-25)^oC=-[0.48g\times 4.184J/g^oC\times (T_{final}-25)^oC]](https://tex.z-dn.net/?f=55g%5Ctimes%200.900J%2Fg%5EoC%5Ctimes%20%28T_%7Bfinal%7D-25%29%5EoC%3D-%5B0.48g%5Ctimes%204.184J%2Fg%5EoC%5Ctimes%20%28T_%7Bfinal%7D-25%29%5EoC%5D)

Thus, the final temperature of the metal block is, 
english:
In physics and chemistry, the law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be conserved over time.
spanish:
En física y química, la ley de conservación de la energía establece que la energía total de un sistema aislado permanece constante; se dice que se conserva con el tiempo.
B) land cools off much faster than water (creating a air region of high density above land and lower density above sea)
Answer:
The correct option is e
Explanation:
Hydrogen bond is an intermolecular interaction/bonding that are formed between an electronegative atom (such as nitrogen, oxygen and fluorine) and a hydrogen atom. They are weak intermolecular bonds compared to covalent bonds but account for the high boiling point of water because of the strong hydrogen bond presence between the water molecules. Water molecules form hydrogen bonds between each other; since an oxygen atom (in a water molecule) has two lone pairs on it's outermost shell, it forms an hydrogen bond with two hydrogen atoms of other water molecule. Due to the fluidity of liquid water molecules, hydrogen bonds keep getting broken (although recreated/formed almost immediately), hence, individual hydrogen bonds in liquid water does not exist for long.
In the explanation above, it was stated that the strength of the hydrogen bond in water is the reason for it's high boiling point. The atoms in a water molecule are bent NOT linear hence the strength of hydrogen bond does not depend on the linearity of the atoms involved in the bond.