Define boiling point. what was the observed boiling point of water for the liquids and solids experiment
1 answer:
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Answer:
Sulfur: -1
Carbon: 0
Nitrogen: 0
Explanation:
The thiocyanate ion SCN- can have only two resonance structures, which are:
S - C ≡ N <--------> S = C = N
In the first structure, we have one single bond and one triple bond, in this case, the negative charge is located in the sulfur. This is because Sulfur have 6 electrons and those electrons are present in the atom, (see picture below), and counting the electron that is sharing with the Carbon, the total electrons that sulfur has is 7 (It has one more than usual). Carbon and nitrogen are already stable with 0 of formal charge, because carbon can only have 4 electrons which 1 is sharing with sulfur and the other 3 with the nitrogen, and nitrogen have 5 electrons, three sharing with carbon and the other two kept it for itself.
In the second structure, the negative charge of the sulfur is transfered to the nitrogen, meaning that it has 6 electrons the nitrogen (formal charge -1) and carbon and sulfur with 4 and 6 electrons respectively.
Between these two structures, the most stable is the first one basically because Sulfur is a better nucleophile than the Nitrogen, and can form stronger hydrogen bond in acid, giving more stable structure.
Answer:
ΔH = - 2020.57 kJ/mol
Explanation:
Given that :
mass of propanol = 1.685 g
the molar molar mass = 60 g/mol
Thus; the number of moles = mass/molar mass
= 1.685 g/60 g/mol
= 0.028 g/mol
However ;
ΔH = heat capacity C × Δ T
Given that:
The temperature increases from 298.00 K to 302.16 K.
Then ;
Δ T = 302.16 K - 298.00 K
Δ T = 4.16 K
heat capacity C = 13.60 kJ/K
∴
ΔH = 13.60 kJ/K × 4.16 K
ΔH = 56.576 kJ
The equation of the given reaction can be represented as :
Thus for 0.028 mol of heat liberated; ΔH = 56.576 kJ
For 1 mole of heat liberated now:
ΔH = 56.576 kJ/0.028 mol
ΔH = 2020.57 kJ/mol
SInce , Heat is liberated, the reaction undergoes an exothermic reaction thus;
ΔH = - 2020.57 kJ/mol
Hope I helped you enjoy your day
