Step one calculate the moles of each element
that is moles= % composition/molar mass
molar mass of Ca = 40g/mol, S= 32 g/mol , O= 16 g/mol
moles of Ca = 29.4 /40g/mol=0.735 moles, S= 23.5/32 =0.734 moles, O= 47.1/16= 2.94 moles
calculate the mole ratio by dividing each mole with smallest mole that is 0.734
Ca= 0.735/0.734= 1, S= 0.734/0.734 =1, O = 2.94/ 0.734= 4
therefore the emipical formula = CaSO4
Electrolytes are substances that produce ions when they dissolve in water.
What are electrolytes?
When some substances are dissolved in water, they undergo physical or chemical changes, creating ions in solution. These substances form an important class of compounds called electrolytes. Substances that do not release ions when dissolved are called non-electrolytes. A substance is said to be a strong electrolyte if the physical or chemical process that produces ions is inherently 100% efficient (all dissolved compounds produce ions). A solute is said to be a weak electrolyte if only a relatively small portion of the solute undergoes ion production processes.
By measuring the electrical conductivity of aqueous solutions containing substances, substances can be identified as strong, weak, or non-electrolyte. To conduct electricity, a substance must contain free-moving charged species. The best known is the conduction of electricity through metal wires. In this case, the mobile charged unit is the electron.
Therefore, Electrolytes are substances that produce ions when they dissolve in water.
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TMS stands for Tetramethylsilane
Formula : Si(CH₃)₄
It is used as internal standard for chemical shift
In TMS all the four methyl groups are similar thus all the 12 hydrogen are chemically equivalent. They will show proton NMR at same level and which will appear as a singlet.
We have defined this singlet to be as reference set as zero.
Generally the other organic compounds show chemical shift downfield.So have positive chemical shift with respect to TMS shift.