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Kazeer [188]
3 years ago
7

Select the correct use of the compound tms in nmr spectroscopy.a. it is a signal-to-noise enhancerb. it is an internal standard

for signal strengthc. it is a commonly used solvent for samplesd. it is an internal standard for chemical shifts
Chemistry
1 answer:
SpyIntel [72]3 years ago
8 0

TMS stands for Tetramethylsilane

Formula : Si(CH₃)₄

It is used as internal standard for chemical shift

In TMS all the four methyl groups are similar thus all the 12 hydrogen are chemically equivalent. They will show proton NMR at same level and which will appear as a singlet.

We have defined this singlet to be as reference set as zero.

Generally the other organic compounds show chemical shift downfield.So have positive chemical shift with respect to TMS shift.

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Which of the following statements is true?
Lera25 [3.4K]

The  statement  which is true is

metals  lose  electrons  to become cations

<u><em>Explanation</em></u>

  • metals tends  to loss electrons to attain  noble gas  electrons  configuration.
  • When metal loses electrons they form a  positive charged ions.
  • The positively charged ion is known as  cations.
  • for  example  sodium metal (Na)  loses  1 electron to form   a cation with  a charge  of positive 1 ( Na^+)
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When a 0.245-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature rises 1.643 ∘C . When a 0.260-g sample
sveticcg [70]

Answer:

The heat of combustion per moles of caffeine is 4220 kJ/mol

Explanation:

Step 1: Data given

⇒ When  benzoic acid sample of 0.245 grams is burned the temperature rise is 1.643 °C

⇒ When 0.260 gram of caffeine is burned, the temperature rise is 1.436 °C

⇒ Heat of combustion of benzoic acid = 26.38 kJ/g

<u>Step 2:</u> Calculate the heat released: for combustion of benzoic acid

0.245 g benzoic acid *  26.38 kJ/g = 6.4631 kJ

<u>Step 3</u>: Calculate the heat capacity of the calorimeter:

c = Q/ΔT

Q = 6.4631 kJ   / 1.643°C = 3.934 kJ/ °C

<u>Step 4:</u> Calculate moles of a 0.260 g sample of caffeine:

Moles caffeine = Mass caffeine / Molar mass caffeine

0.260 grams/ 194.19 g/mol  = 0.0013389 moles

Step 5: Calculate heat released: for combustion of caffeine

Q = c * ΔT

Q = 3.934 kJ/°C * 1.436 °C = 5.65 kJ

Step 6: Calculate the heat of combustion per mole of caffeine  

5.65 kJ  /  0.0013389 moles = 4219.9 kJ/mol  ≈ 4220 kJ/mol

The heat of combustion per moles of caffeine is 4220 kJ/mol

4 0
3 years ago
PLEASE HELPP!!!!
Alenkinab [10]

Answer:

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The ion charge is positive 1

K the valency electrons is 1

The ion charge is positive 1

Explanation:

Mg the valency electron is 2 The ion charge is positive 2

Ca the valency electron is 2 The ion charge is positive 2

Al the valency electron is 3 The ion charge is positive 3

O the valency electron is 2 The ion charge

is negative 2

F the valency electron is 1 The ion charge is negative 1

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3 0
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Complete the following precipitation reactions with balanced molecular, total ionic, and net ionic equations:
Dmitry [639]

Molecular equation

Hg₂(NO₃)₂ (aq) + KI(aq) ⇒Hg₂I₂(s) + 2KNO₃(aq)

Total Ionic equation

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Net Ionic equation

Hg²⁺(aq) + 2I⁻(aq)  ⇒ Hg₂I₂(s)

<h3>What is the molecular equation?</h3>

Sometimes, a balanced equation is all that is used to refer to a chemical equation. Any ionic substances or acids are represented using their chemical formulas as neutral compounds in a molecular equation. Each substance's state is described in parenthesis after the formula. A complete ionic equation also contains the spectator ions, whereas a net ionic equation just displays the chemical species that are involved in a reaction.

The steps listed below can be used to determine the net ionic equation for a specific reaction:

Include the states of each chemical in the balanced molecular equation for the reaction.

To know more about the molecular equation, visit:

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4 0
1 year ago
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