<u>Answer:</u> The mass percent of potassium bromide in the mixture is 9.996%
<u>Explanation:</u>
- To calculate the number of moles, we use the equation:
.....(1)
<u>For lead (II) bromide:</u>
Given mass of lead (II) bromide = 0.7822 g
Molar mass of lead (II) bromide = 367 g/mol
Putting values in equation 1, we get:

- The chemical equation for the reaction of lead (II) nitrate and potassium bromide follows:

By Stoichiometry of the reaction:
1 mole of lead (II) bromide is produced from 2 moles of potassium bromide
So, 0.0021 moles of lead (II) bromide will be produced from =
of potassium bromide
- Now, calculating the mass of potassium bromide by using equation 1, we get:
Molar mass of KBr = 119 g/mol
Moles of KBr = 0.0042 moles
Putting values in equation 1, we get:

- To calculate the percentage composition of KBr in the mixture, we use the equation:

Mass of mixture = 5.000 g
Mass of KBr = 0.4998 g
Putting values in above equation, we get:

Hence, the percent by mass of KBr in the mixture is 9.996 %