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Reika [66]
3 years ago
12

How many ammonium ions and how many sulfate ions are present in an 0.260 mol sample of (nh4)2so4?

Chemistry
1 answer:
Anna11 [10]3 years ago
4 0
The question requires that you assume complete ionization of the compound. This is:

(NH4)2 SO4 → 2 NH4 (+) + SO4 (2-)

Then, 1 mol of (NH4)2 SO4 produces 3 moles of ions: 2 moles of NH4 (+) and 1 mol of SO4 (2-)

=> 0.26 * 2 moles of NH4(+) = 0.52 moles of NH4 (+)

0.26 * 1 mol of SO4 (2-) = 0.26 moles of SO4 (2-).

Answer: 0.52 moles of ammonium ions and 0.26 moles of sulfate.ions.


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Answer:

Therefore  \bigtriangledown H^\circ_{rxn}= -1835 KJ

Explanation:

Enthalpy is denoted by H.

Enthalpy: Total heat change in a chemical reaction is called enthalpy.

The change of entalpy of a reaction is denoted by \bigtriangledown H^\circ_{rxn}

Hass's Law:The change in enthalpy of any process can be determined by calculating the sum of change in enthalpy of each of the steps involved in the process.

g= gas

S= solid

P₄(g)+10Cl₂(g)→ 4Cl₅(s)       \bigtriangledown H^\circ_{rxn}=?

PCl₅(s)→ PCl₃(g)+Cl₂(g) .......(1)       \bigtriangledown H^\circ_{rxn}= +157KJ

P₄(g)+6Cl₂(g)→  4PCl₃(g).............(2)     \bigtriangledown H^\circ_{rxn}= -1207 KJ

If we flip a reaction the value of enthalpy will be change positive to negative or nagative to positive but the numerical value will be remain same.

We need rearrange the equation (1) because in the required equation Cl₂ is on the left side. So we flip the first equation.

PCl₃(g)+Cl₂(g)→PCl₅(s)......(3)          \bigtriangledown H^\circ_{rxn}= -157KJ

Multiplying 4 with equation (3)

4 PCl₃(g)+4Cl₂(g)→4PCl₅(s)......(4)          \bigtriangledown H^\circ_{rxn}=4×( -157)KJ= -628 KJ

Adding equation (2) and (4) we get

P₄(g)+6Cl₂(g)+4 PCl₃(g)+4Cl₂(g)→4PCl₃(g)+4PCl₅(s)    \bigtriangledown H^\circ_{rxn}=( -1207-628)KJ

⇒P₄(g)+10Cl₂(g)→4PCl₃(g)-4PCl₃(g)+4PCl₅(s)      \bigtriangledown H^\circ_{rxn}= - 1835KJ

⇒P₄(g)+10Cl₂(g)→ 4Cl₅(s)       \bigtriangledown H^\circ_{rxn}= -1835 KJ

Therefore  \bigtriangledown H^\circ_{rxn}= -1835 KJ

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