What can destroy buffer solution?

Bond breaking process is an endothermic process in which energy is absorbed from the surrounding.
Whenever a bond is broken, the bond energy value is positive but when a bond is formed, the bond energy value is given a negative sign.

For a bond formation process in which hydrogen atoms are bonded covalently, energy is usually released.

Learn more:

#learnwithBrainly

5 0

3 years ago

Nimfa-mama [501]

<h2>Heptene formed is -</h2><h2> $CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr$ </h2>

Explanation:

The two possibilities when the peroxide is not present

$CH_{3}-CH_{2}-CH_{2}-CH_{2}-CH_{2}-C$ ≡ $CH +HBr$ → $CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_{2}$

$CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_2$ + HBr → $CH_3-CH_2-CH_2-CH_2-CH_2-CBr_2-CH_3$

In presence peroxide,

$CH_3-CH_2-CH_2-CH_2-CH_2-C$ ≡ $CH$ + HBr → $CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr$

When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.

This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
One mole of HBr adds to one mole of 1-heptane.
The structure of heptene formed is -

$CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr$

5 0

3 years ago