Eggshells are made primarily of calcium carbonate. The acid in vinegar softens the calcium of the eggshell. Adding a little vinegar to the water when boiling eggs is an old cook’s trick that makes them easier to peel.
A link to this experiment is below in the comment box
A space-filling model shows the relative amount of space each atom takes up. In other words, a space-filling model can show relative sizes of atoms. However, unlike ball-and-stick or structural models, space-filling models do not show bond lengths clearly. Bonds are not really like sticks in a ball-and-stick model.
In a neutral atom they are both equal, and their even quantities makes the atom neutral...