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tangare [24]
3 years ago
13

What happens when a crystal potassium nitrate is added to a saturated solution as it cooled

Chemistry
1 answer:
coldgirl [10]3 years ago
3 0
Crystals will begin to form. crystals form from c<span>ertain molecules in the liquid gather together as they attempt to become stable. they </span>do<span> this in a uniform and repeating pattern that </span>forms<span> the </span>crystal<span>.in nature, </span>crystals<span> can </span>form<span> when liquid rock, called magma, cools.if it cools slowly then </span>crystals<span> may</span>form<span>.</span>  hope it helps :)
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Lead all chlorate is mixed with hydrolylic acid. Each solution is 0.85 molar. Write balanced, molecular, ionic, and net equation
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Answer:

Here's what I get  

Explanation:

Solubility rules

  • Salts containing halides are generally soluble. Important exceptions to this rule are halides of silver, mercury, and lead(II).
  • All acetates, chlorates, and perchlorates are soluble

So, PbCl₂ is insoluble, and Pb(ClO₃)₂ is soluble.

1. "Molecular" equation

\rm Pb(ClO_{3})_{2}(aq) + 2HCl(aq) \longrightarrow \, PbCl_{2}(s) + 2HClO_{3}(aq)

2. Ionic equation

Convert the soluble salts to their hydrated ions.

HCl and HClO₃ are strong acids. Convert them to their ions.

\rm Pb^{2+}(aq) + 2ClO_{3}^{-}(aq)+ 2H^{+}(aq) + 2Cl^{-}(aq) \longrightarrow \, PbCl_{2}(s) + 2H^{+}(aq) + 2ClO_{3}^{-}(aq)

3. Net ionic equation

Cancel all ions that appear on both sides of the reaction arrow (in boldface).

\rm {Pb}^{2+}(aq) + \textbf{2ClO}_{3}^{-}(aq)+ \textbf{2H}^{+}(aq) + 2Cl^{-}(aq) \longrightarrow \, PbCl_{2}(s) + \textbf{2H}^{+}(aq) + \textbf{2ClO}_{3}^{-}(aq)

The net ionic equation is

\rm {Pb}^{2+}(aq) + 2Cl^{-}(aq) \longrightarrow \, PbCl_{2}(s)

4. Theoretical yield

We have the volumes and concentrations of two reactants, so this is a limiting reactant problem.  

We know that we will need a balanced equation with masses, moles, and molar masses of the compounds involved.  

(i). Gather all the information in one place with molar masses above the formulas and masses below them.  

M_r:                                                   278.11

                        Pb(ClO₃)₂ + 2HCl ⟶ PbCl₂ + 2HClO₃

Volume/mL:      125             95

c/mol·L⁻¹:          0.85         0.85

(ii) Calculate the moles of each reactant  

\text{Moles of Pb(ClO$_{3}$)}_{2} = \text{0.125 L} \times \dfrac{\text{0.85 mol}}{\text{1 L }} = \text{0.1062 mol}\\\text{Moles of HCl} = \text{0.095 L} \times \dfrac{\text{0.85 mol}}{\text{1 L }} = \text{0.08075 mol}

(iii) Identify the limiting reactant  

Calculate the moles of PbCl₂ we can obtain from each reactant.  

From Pb(ClO₃)₂:

The molar ratio of PbCl₂:Pb(ClO₃)₂ is 2:2

Moles of PbCl₂ = 0.1062 × 2/2 =0.1062 mol PbCl₂

From HCl :

The molar ratio of PbCl₂:HCl is 1 mol PbCl₂:2 mol HCl.

Moles of PbCl₂ = 0.08075 × 1/2 = 0.04038 mol PbCl₂

The limiting reactant is HCl because it gives the smaller amount of PbCl₂.

(iv) Calculate the theoretical yield of PbCl₂.

\text{Theor. yield of PbCl}_{2} = \text{0.0438 mol} \times \dfrac{\text{278.11 g}}{\text{ 1 mol}} = \textbf{11.2 g}

5. Calculate the actual yield of PbCl₂

\text{Actual yield} = \text{11.2 g theor.} \times \dfrac{\text{ 68 g actual}}{\text{100 g theor,}} = \textbf{7.6 g}

6. Calculate [ClO₃⁻]

Original concentration of Pb(ClO₃)₂ = 0.85 mol·L⁻¹

Original concentration of ClO₃ = 2 × 0.85  = 1.70 mol·L⁻¹

The solution was diluted by the addition of HCl.

Total volume = 125 + 95 =220 mL

                           c₁V₁ = c₂V₂

1.70 mol·L⁻¹ × 125 mL = c₂ × 220 mL

            212.5 mol·L⁻¹ = 200 c₂

 c₂ = (212.5 mL)/200 =  1.06 mol·L⁻¹

7. Calculate [Pb²⁺].

Moles of Pb²⁺ originally present = 0.1062 mol

              Moles of Pb²⁺removed = 0.04038 mol

           Moles of Pb²⁺ remaining = 0.0659 mol

c = 0.0659 mol/0.220 L = 0.299 mol·L⁻¹

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