Answer:
[Cu²⁺] = 2.01x10⁻²⁶
Explanation:
The equilibrium of Cu(CN)₄²⁻ is:
Cu²⁺ + 4CN⁻ ⇄ Cu(CN)₄²⁻
And Kf is defined as:
Kf = 1.0x10²⁵ = [Cu(CN)₄²⁻] / [Cu²⁺] [CN⁻]⁴
As Kf is too high you can assume all Cu²⁺ is converted in Cu(CN)₄²⁻ -Cu²⁺ is limiting reactant-, the new concentrations will be:
[Cu²⁺] = 0
[CN⁻] = 0.33M - 4×2.2x10⁻³ = 0.3212M
[Cu(CN)₄²⁻] = 2.2x10⁻³
Some [Cu²⁺] will be formed and equilibrium concentrations will be:
[Cu²⁺] = X
[CN⁻] = 0.3212M + 4X
[Cu(CN)₄²⁻] = 2.2x10⁻³ - X
<em>Where X is reaction coordinate</em>
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Replacing in Kf equation:
1.0x10²⁵ = [2.2x10⁻³ - X] / [X] [0.3212M +4X]⁴
1.0x10²⁵ = [2.2x10⁻³ - X] / 0.0104858X + 0.524288 X² + 9.8304 X³ + 81.92 X⁴ + 256 X⁵
1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ = 2.2x10⁻³ - X
1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ - 2.2x10⁻³ = 0
Solving for X:
X = 2.01x10⁻²⁶
As
[Cu²⁺] = X
<h3>[Cu²⁺] = 2.01x10⁻²⁶</h3>
Answer:
The average atomic mass is closer to Si- 28 because this isotope is present in more percentage in the sample.
Explanation:
Given data:
Atomic mass of silicon= ?
Percent abundance of Si-28 = 92.21%
Atomic mass of Si-28 = 27.98 amu
Percent abundance of Si-29 = 4.70%
Atomic mass of Si-29 = 28.98 amu
Percent abundance of Si-30 = 3.09%
Atomic mass of Si-30 = 29.97 amu
Solution:
Average atomic mass = (abundance of 1st isotope × its atomic mass) +(abundance of 2nd isotope × its atomic mass)+(abundance of 2nd isotope × its atomic mass) / 100
Average atomic mass = (92.21×27.98)+(4.70×28.98)+(3.09×29.97) /100
Average atomic mass = 2580.04 +136.21+92.61 / 100
Average atomic mass = 2808.86 / 100
Average atomic mass = 28.08amu.
The average atomic mass is closer to Si- 28 because this isotope is present in more percentage in the sample.
Cells are surrounded by #2 , Cell membrane and Cell wall thats what protects the cell
