Answer:
The correct answer should be 12.72 pH of the mixed solution and 9.94g mass of solid BASO4 formed.
Explanation:
The molecules of Ba(OH)2 are : 1.00M x 0.05L = 0.05 ( moles )
The molecules of H2SO4 are : 0.494M x 0.0864L = 0.0426816
Ba(OH)2 + H2SO4 ----> BaSO4 + 2 H2O
0.0426816<--- 0.0426816
The mixed solution is Ba(OH)2 with 0.05 - 0.0426816 = 0.0073184
The concentration of mixed solution is : 0.0073184 : ( 0.05 + 0.0864 ) = 0.054 M
The pH of mixed solution is 14 - -log[0.054] = 14 - 1.27 = 12.73 PH
And the mass of BaSO4 is 0.0426816 x ( 137 + 32 + 16 x 4 ) = 9.94 gams.
<h2><em><u>
Answer - </u></em>b) Be the same as in the second method</h2>
<h3>Brief explanation:</h3>
Enthalpy is an state function that does not depend on the path followed to carry out the reaction but depends upon the initial and final state of system. In above statement both the reaction are same hence the enthalpy change would also be same. This can also be represent in the form of equation,
<h3> ΔHsys = Hf - Hi</h3>
Where,
- ΔHsys is change in enthalpy of system
- Hf is enthalpy of reaction at final state
- Hi is enthalpy of reaction at initial state
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