Answer:
7,94 minutes
Explanation:
If the descomposition of HBr(gr) into elemental species have a rate constant, then this reaction belongs to a zero-order reaction kinetics, where the r<em>eaction rate does not depend on the concentration of the reactants. </em>
For the zero-order reactions, concentration-time equation can be written as follows:
[A] = - Kt + [Ao]
where:
- [A]: concentration of the reactant A at the <em>t </em>time,
- [A]o: initial concentration of the reactant A,
- K: rate constant,
- t: elapsed time of the reaction
<u>To solve the problem, we just replace our data in the concentration-time equation, and we clear the value of t.</u>
Data:
K = 4.2 ×10−3atm/s,
[A]o=[HBr]o= 2 atm,
[A]=[HBr]=0 atm (all HBr(g) is gone)
<em>We clear the incognita :</em>
[A] = - Kt + [Ao]............. Kt = [Ao] - [A]
t = ([Ao] - [A])/K
<em>We replace the numerical values:</em>
t = (2 atm - 0 atm)/4.2 ×10−3atm/s = 476,19 s = 7,94 minutes
So, we need 7,94 minutes to achieve complete conversion into elements ([HBr]=0).
Answer:
Rate = k [OCl] [I]
Explanation:
OCI+r → or +CI
Experiment [OCI] M I(-M) Rate (M/s)2
1 3.48 x 10-3 5.05 x 10-3 1.34 x 10-3
2 3.48 x 10-3 1.01 x 10-2 2.68 x 10-3
3 6.97 x 10-3 5.05 x 10-3 2.68 x 10-3
4 6.97 x 10-3 1.01 x 10-2 5.36 x 10-3
The table above able shows how the rate of the reaction is affected by changes in concentrations of the reactants.
In experiments 1 and 3, the conc of iodine is constant, however the rate is doubled and so is the conc of OCl. This means that the reaction is in first order with OCl.
In experiments 3 and 4, the conc of OCl is constant, however the rate is doubled and so is the conc of lodine. This means that the reaction is in first order with I.
The rate law is given as;
Rate = k [OCl] [I]
