Draw the products of Claisen condensation of (a) ethyl propanoate; (b) ethyl-3-methylbutanoate; (c) ethyl pentanoate. For each,
the base used is sodium ethoxide and the solvent is ethanol.
1 answer:
Answer:
Structures of products has been shown below
Explanation:
- In claisen condensation, two ester molecules combines with each other through nucleophilic acyl substitution resulting formation of a
-ketoester.
- At first, one ester molecule gets deprotonated in presence of a strong base e.g. NaOEt yielding a carbanion.
- The carbanion then gives nucleophilic acyl substitution reaction with another ester molecule to replace alkoxy group present in ester group
- General reaction mechanism of claisen condensation along with products of given esters are shown below.
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Organometallic chemistry is the study of organometallic compounds, which are substances that contain at least one chemical bond between a carbon atom from an organic molecule and a metal. These substances include alkali, alkaline earth, and transition metals, as well as metalloids like boron, silicon, and selenium. In addition to links to organyl fragments or molecules, bonds to 'inorganic' carbon, such as those to carbon monoxide (metal carbonyls), cyanide, or carbide, are also typically regarded as organometallic. Although they are not strictly speaking organometallic compounds, some similar compounds, such as transition metal hydrides and metal phosphine complexes, are frequently included in discussions of such substances. The phrase "metalorganic compound," which is comparable but different, describes molecules that contain metals but do not have direct metal-carbon bonds but do have organic ligands.
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