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Vlada [557]
3 years ago
15

Draw the products of Claisen condensation of (a) ethyl propanoate; (b) ethyl-3-methylbutanoate; (c) ethyl pentanoate. For each,

the base used is sodium ethoxide and the solvent is ethanol.

Chemistry
1 answer:
Nonamiya [84]3 years ago
5 0

Answer:

Structures of products has been shown below

Explanation:

  • In claisen condensation, two ester molecules combines with each other through nucleophilic acyl substitution resulting formation of a \beta-ketoester.
  • At first, one ester molecule gets deprotonated in presence of a strong base e.g. NaOEt yielding a carbanion.
  • The carbanion then gives nucleophilic acyl substitution reaction with another ester molecule to replace alkoxy group present in ester group
  • General reaction mechanism of claisen condensation along with products of given esters are shown below.

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The pH of a solution is measured as 4.5. What is the hydrogen ion concentration of the solution?
Bond [772]

Answer:

[H⁺] =  3.16 × 10⁻⁵ mol/L

Explanation:

Given data:

pH of solution = 4.5

Hydrogen ion concentration = ?

Solution;

pH = -log [H⁺]

we will rearrange this formula:

[H⁺] =  10∧-pH

[H⁺] = 10⁻⁴°⁵

[H⁺] =  3.16 × 10⁻⁵ mol/L

4 0
3 years ago
An object has a mass of 4 grams and a volume of 2 cm^3.what is the density of the object?
stellarik [79]

Answer:

2.0 grams per cubic centimeter

Explanation:

(You can refer to the DMV triangle to help you solve this!)

Density = Mass/Volume

Density = 4.0g/2.0cm3

Density = 2.0g/cm3

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3 0
3 years ago
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What is the maximum amount of HCl, in grams, that can be produced if 37.5 g of BCl3 and 60.0 g of H2O are reacted according to t
Rus_ich [418]
Ooooh boy alright. So, this may or may not be a limited reactant problem so we need to first find out of it is.

First, how many moles of each substance are there

the molar mass of BCl3 is <span>117.17 grams so 37.5 g / 117.17 is ~ .32 mol.
The molar mass of H2O is 18.02 so 60 / 18.02 is ~ 3.33 mol.

Now, for every 1 mole of BCl3, there are 3 moles of HCl created. Therefore, BCl3 can create ~ .96 moles.
For every 3 moles of H2O, there are 3 moles of HCl created. Therefore, HCl can create ~3.33 moles.

But, there is not enough BCl3 to support that 3.33 moles, only enough for .96 moles, therefore BCl3 is the limiting reactant. Now, to answer the question, simply multiply .96 moles by the molar mass of HCl.

.96 x 36.46 = ~35 g</span>
6 0
3 years ago
How are the following aspects of a reaction affected by the addition of a catalyst? 1) activation energy of the reverse reaction
snow_tiger [21]

These are four questions and four answers.

Answers:

1) activation energy of the reverse reaction

     b. Decreased

2) Rate of the forward reaction

    a. Increased

3) Rate of the reverse reaction

    a. Increased

4) Activation energy of the forward reaction

    b. decreased

Explanation:

<em>Activarion energy</em> is the energy required by the reactants to form the intermediate transition state and become products.

<em>Catalysts</em> are substances that change the path of the chemical reactions, lowering the activation energy, and thus speeding up the rate of the reactions, since the products can reach the new lower activation energy faster.

The equilibrium reactions are the chemical process in which two reactions, the <em>forward and the reverese reactions</em>, occur simultaneously and at the same rate.  The equlibrium reactions may be represented by:

  • A ⇄ B

Where A → B is the direct or forward reaction, and A ← B is the reverse reaction (note the inversed arrow, from right to left).

For the direct reaction A represents the reactants and B represents the products. On the other hand, B represents the reactants and A represents the reactants of the reverse reaction and A. This, is A is the reactant of the forward reaction and the product of the reverse reaction, while B is the reactant of the reverse reaction and the product of the forward reaction.

Since, <em>the addition of a catalyst</em> lowers the activation energy of the process, the new activation energy is lower for both the forward and the reverse reaction, meaning that:

1. <em>The activation energy of the reverse reaction is decreased</em> (option b. of the first question)

2.<em> The rate of the forward reaction is increased</em> (option a. of the second question)

3. <em>The rate of the reverse reaction is increased</em> (option a. of the third question).

4. <em>Activation energy of the forward reaction is decreased</em> (option b. of the fourth question).

In summary, the addition of a catalyst decreases the activation energy for both forward and reverse reactions, and increases the rate of both forward and reverse reactions.

3 0
3 years ago
Read 2 more answers
Help! Need it ASAP!<br> Is steam and vapour different? If they are then how are they different?
Alexxx [7]

Answer:

Explanation:

Water vapor is when water molecules are present in the air, while steam is water heated to the point that it turns into gas. In simplified science, both are referred to as the gaseous state of water. Steam is usually white or translucent in nature, while water vapor can be clear or translucent.

Steam is simply, water vapor. Hence, the key difference between steam and vapor is that steam is the gaseous state of water whereas vapor is the gaseous state of any substance. Moreover, steam is typically invisible while the vapor of some substances is colorful.

8 0
3 years ago
Read 2 more answers
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