Answer is: increase the concentration of NiCO₄ and <span>withdraw CO from the products as it is forming.
Balanced chemical reaction: NiCO</span>₄(g) ⇄ Ni(s) + 4CO(g).
According to Le Chatelier's Principle the position of equilibrium
moves to counteract the change:
1) the position of equilibrium will move to the right, so
that the concentration of nickel carbonyl gas decreases again and produce more nickel.
2) the position of equilibrium will move to the right, if we decrease concentration of carbon monoxide, more nickel carbonyl gas will decompose and produce more nickel.
Answer:
Pp O2 = 82.944 KPa
Explanation:
heliox tank:
∴ %wt He = 32%
∴ %wt O2 = 68%
∴ Pt = 395 KPa
⇒ Pp O2 = ?
assuming a mix of ideal gases at the temperature and volumen of the mix:
∴ Pi = RTni/V
∴ Pt = RTnt/V
⇒ Pi/Pt = ni/nt = Xi
⇒ Pi = (Xi)*(Pt)
∴ Xi: molar fraction (ni/nt)
⇒ 0.68 = mass O2/mass mix
assuming mass mix = 100 g
⇒ mass O2 = 68 g
∴ molar mass O2 = 32 g/mol
⇒ moles O2 = (68 g)(mol/32 g) = 2.125 mol O2
⇒ mass He = 32 g
∴ molar mass He = 4.0026 g/mol
⇒ moles He = (32 g)(mol/4.0026 g) = 7.995 mol He
⇒ nt = nO2 + nHe = 2.125 mol + 7.995 mol = 10.12 moles
molar fraction O2:
⇒ X O2 = nO2/nt = (2.125 mol/10.12 mol) = 0.2099
⇒ Pp O2 = (X O2)(Pt)
⇒ Pp O2 = (0.2099)(395 KPa)
⇒ Pp O2 = 82.944 KPa
This is an incomplete question, here is a complete question.
The rearrangement of methyl isonitrile (CH₃NC) to acetonitrile (CH₃NC) is a first-order reaction and has a rate constant of 5.11 × 10⁻⁵ s⁻¹ at 472 K. If the initial concentration of CH₃NC is 3.00 × 10⁻² M :
How many hours will it take for the concentration of methyl isonitrile to drop to 14.0 % of its initial value?
Answer : The time taken will be, 10.7 hours
Explanation :
Expression for rate law for first order kinetics is given by:
where,
k = rate constant = 
t = time passed by the sample = ?
a = let initial amount of the reactant = 100
a - x = amount left after decay process = 14 % of 100 = 14
Now put all the given values in above equation, we get
Therefore, the time taken will be, 10.7 hours
Actualy the answer is Lower pressure causes the papers to come closer together.
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