Answer:
Explanation:
The formula of the reaction:
KClO₂ → KCl + O₂
To assign oxidation numbers, we have to obey some rules:
- Elements in an uncombined state or one whose atoms combine with one another to form molecules have an oxidation number of zero.
- The charge on simple ions signifies their oxidation number.
- The algebraic sum of all the oxidation number of all atoms in a neutral compound is zero. For radicals with charges, their oxidation number is the charge.
The oxidation number of K in KClO₂:
K + (-1) + 2(-2) = 0
K-5 = 0
K = +5
The oxidation number of K in KCl:
K + (-1) = 0
K = +1
The oxidation number Cl in KClO₂ is -1
For Cl in KCl, the oxidation number is -1
For O in KClO₂, the oxidation number is (2 x -2) = -4
For O in O₂, the oxidation number is 0
K moves from an oxidation state of +5 to +1. This is a gain of electrons and K has undergone reduction. We then say K is reduced.
O moves from an oxidation state of -4 to 0. This is a loss of electrons and O has undergone oxidation. We say O is oxidized.
The value of ΔG° at this temperature is -18034.18 J/mol
Calculation,
Given information
formation constant (Kf)= 1.7 × 
Universal gas constant (R) = 8.314 J/K• mol
Temperature = 25° C = 25 °C + 273 = 300 K
Formula used:
ΔG° = -RT㏑Kf
By putting the valur of R,T, Kf we get the value of ΔG°
ΔG° = - 8.314 J/K• mol×300K㏑ 1.7 ×
ΔG° = -2494.2㏑ 1.7 × = -18034.18 J/mol
So, change in standard Gibbs's free energy is -18034.18 J/mol
Learn about formation constant
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Answer: Igneous rocks may be simply classified according to their chemical/mineral composition as felsic, intermediate, mafic, and ultramafic, and by texture or grain size: intrusive rocks are course grained (all crystals are visible to the naked eye) while extrusive rocks may be fine-grained (microscopic crystals) or glass.
Explanation: Hope this helped! :)
Answer:
Xe:[Kr]4d¹⁰5(sp³d³)₆⁺² => Octahedral Geometry (AX₆)⁺²
Explanation:
Xe:[Kr]4d¹⁰(5s²5p₋₁²p₀²p₁²5d₋₂d₋₁d₀)⁺² => Xe[Kr]5(sp³d³)₆²
Ca. #Valence e⁻ = Xe + 6F - 2e⁻ = 1(8) + 6(7) - 2 = 48
Ca. #Substrate e⁻ = 6F = 6(8) = 48
#Nonbonded free pairs e⁻ = (V - S)/2 = (48 - 48)/2 = 0 free pairs
#Bonded pairs e⁻ = 6F substrates = 6 bonded pairs
BPr + NBPr = 6 + 0 = 6 e⁻ pairs => Geometry => [AX₆]⁺² => Octahedron
Xe:[Kr]4d¹⁰(5s²5p₋₁²p₀²p₁²5d₋₂d₋₁d₀)⁺² => Xe[Kr]5(sp³d³)₆⁺²
XeF₆⁺² => 6(sp³d³) hybrid orbitals => Octahedral Geometry (AX₆)
