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Stels [109]
3 years ago
12

How does a buffer resist change in pH upon addition of a strong acid? The strong acid reacts with the strong base in the buffer

to form a salt, which produces few H+ ions in solution and therefore only a little change in pH. The strong acid reacts with the weak base in the buffer to form a weak acid, which produces few H+ ions in solution and therefore only a little change in pH. The strong acid reacts with the weak acid in the buffer to form a weak base, which produces few H+ ions in solution and therefore only a little change in pH.
Chemistry
1 answer:
MrRa [10]3 years ago
4 0

Answer:

The strong acid reacts with the weak base in the buffer to form a weak acid, which produces few H+ ions in solution and therefore only a little change in pH.

Explanation:

When a strong acid is added to the buffer, the acid dissociates and furnish hydrogen ions which combine with the conjugate of the weak acid, forming weak acid. The weak acid dissociates to only some extent and can furnish only some protons and there is no significant change in the pH.

Hence, option B is correct.

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A chemist fills a reaction vessel with 9.20 atm nitrogen monoxide (NO) gas, 9.15 atm chlorine (CI) gas, and 7.70 atm nitrosyl ch
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Answer:

The reactions free energy \Delta G = -49.36 kJ

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From the question we are told that

      The pressure of (NO) is P_{NO} = 9.20 \ atm

      The  pressure of  (Cl) gas is  P_{Cl} = 9.15 \ atm

       The  pressure of nitrosly chloride (NOCl) is P_{(NOCl)} = 7.70 \ atm

The reaction is

              2NO_{(g)} + Cl_2 (g)    ⇆   2 NOCl_{(g)}

 From the reaction we can  mathematically evaluate the \Delta G^o (Standard state  free energy ) as

                    \Delta G^o = 2 \Delta G^o _{NOCl} -   \Delta G^o _{Cl_2}  - 2 \Delta G^o _{NO}

The Standard state  free energy for NO is  constant with a value  

                 \Delta G^o _{NO} = 86.55 kJ/mol

 The Standard state  free energy for Cl_2 is  constant with a value                  

             \Delta G^o _{Cl_2} = 0kJ/mol

 The Standard state  free energy for NOCl is  constant with a value

         \Delta G^o _{NOCl} =66.1kJ/mol

Now substituting this into the equation

        \Delta G^o = 2 * 66.1 - 0 - 2 * 87.6

                = -43 kJ/mol

The pressure constant is evaluated as

         Q =  \frac{Pressure \ of  \ product }{ Pressure  \ of \ reactant }

Substituting  values  

        Q = \frac{(7.7)^2 }{(9.2)^2 (9.15) } = \frac{59.29}{774.456}

           = 0.0765

The free energy for this reaction is evaluated as

           \Delta  G  =  \Delta  G^o  + RT ln Q

Where R is gas constant with a value  of  R = 8.314 J / K \cdot mol

          T is temperature in K  with a given value of  T = 25+273 = 298 K

   Substituting value

                \Delta  G  = -43 *10^{3} + 8.314 *298 * ln [0.0765]

                       = -43-6.36

                      \Delta G = -49.36 kJ

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