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shtirl [24]
3 years ago
12

During the recrystallization of a solid, the sample is dissolved in hot solvent then filtered while hot. The filtrate is allowed

to cool and the mixture is filtered a second time. What effect will result if the filtrate solution is cooled too rapidly? Small impure crystals will form. Small pure crystals will form. The maximum amount of the compound as a purified solid will be obtained. Large impure crystals will form.
Chemistry
1 answer:
Inessa [10]3 years ago
5 0

Answer:

<em>If the filtrate solution is cooled too rapidly, Small pure crystals will form.</em>

Explanation:

The crystals form by two processes, nucleation and particle growth. Thus the size of the crystals is determined by the predominance between one or the other. In order to obtain the lower number of nucleus  and the larger crystals it is necessary to cool the solution slowly. If the solution  is cooled too rapidly there is no time to the particles growth and the result will be small crystals. But also, a fast cooling avoid the impurities in the crystals.

   

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Answer:

See explanation.

Explanation:

Hello,

In this case, we can show how the empirical formula is found by following the shown below procedure:

1. Compute the moles of carbon in carbon dioxide as the only source of carbon at the products:

n_C=0.01962molCO_2*\frac{1molC}{1molCO_2} =0.01962molC

2. Compute the moles of hydrogen in water as the only source of hydrogen at the products:

n_H=0.01961molH_2O*\frac{2molH}{1molH_2O}=0.03922molH

3. Compute the mass of oxygen by subtracting the mass of both carbon and hydrogen from the 0.4647-g sample:

m_O=0.4647g-0.01962molC*\frac{12gC}{1molC}-0.03922molH*\frac{1gH}{1molH}  =0.1900gO

4. Compute the moles of oxygen by using its molar mass:

n_O=0.1900gO*\frac{1molO}{16gO}=0.01188molO

5. Divide the moles of carbon, hydrogen and oxygen by the moles of oxygen (smallest one) to find the subscripts in the empirical formula:

C=\frac{0.01962}{0.01188}=1.65\\ \\H=\frac{0.03922}{0.01188} =3.3\\\\O=\frac{0.01188}{0.01188} =1

6. Search for the closest whole number (in this case multiply by 2):

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Moreover, the empirical formula suggests this compound could be carboxylic acid since it has two oxygen atoms, nevertheless, this is not true since the molar mass is 222.27 g/mol, therefore, we should compute the molar mass of the empirical formula, that is:

M=12*3+1*6+16*2=74g/mol

Which is about three times in the molecular formula, for that reason, the actual formula is:

C_9H_{18}O_6

It suggest that the compound has a highly oxidizing character due to the presence of oxygen, therefore, we cannot predict the distribution of the functional groups as it could contain, carboxyl, carbonyl, hydroxyl or even peroxi.

Best regards.

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