The best answer among the choices listed is the third option. The rate over the course of a reaction <span>decreases because the concentration of reactants decreases. As the concentration of the reactants decreases, there is less particles to form the products therefore less rate.</span>
We will use this two reaction equation:
H2SO3 + H2O ↔ H3O+ + HSO3- Ka1 = 1.3 x 10^-2
HSO3- + H2O ↔ H3O+ + SO3 2- Ka2= 6.3 x 10^-8
we will use the ICE table for the first equation:
H2SO3 + H2O ↔ H3O+ + HSO3-
initial 0.025 0 0
change -X +X +X
Equ (0.025-X) X X
Ka1 = [H3O+] [HSO3-] / [H2SO3]
1.3 x 10^-2 = X^2 / (0.025 - X) by solving for X
∴ X = 0.0127
when [H3O+] = X
∴[H3O+] = 0.0127 M
and when [HSO3-] = X
∴[HSO3-] = 0.0127 M
and when [H2SO3] = 0.025 - X
∴[H2SO3] = 0.025 - 0.0127
= 0.0123 M
when Kw = [OH-][H3O+]
and Kw = 1.1 x 10^-14 / 0.0127
∴[OH-] = 1.1 x 10^-14 / 0.0127
= 8.66 x 10^-13 M
- by using the ICE table for the second equation:
HSO3- + H2O ↔ H3O+ + SO3 2-
initial 0.0127 0.0127 0
change -X +X +X
Equ (0.0127-X) (0.0127+X) X
when Ka2 = [SO32-] [H3O+] / [HSO3-]
by substitution:
6.3 x 10^-8 = X(0.0127+X) / (0.0127-X)
as the Ka2 is so small so we can assume that (0.01271 + X) & (0.01271-X) = 0.01271 and neglect X
6.3 x 10^-8 = 0.0127X /0.0127
∴X = 6.3 x 10^-8
when [SO3 2-] = X
∴[SO32-] = 6.3 x 10^-8
False. gases have to greatest freedom of motion
Answer:
the initial temperature of the iron sample is Ti = 90,36 °C
Explanation:
Assuming the calorimeter has no heat loss to the surroundings:
Q w + Q iron = 0
Also when the T stops changing means an equilibrium has been reached and therefore, in that moment, the temperature of the water is the same that the iron ( final temperature of water= final temperature of iron = T )
Assuming Q= m*c*( T- Tir)
mc*cc*(T-Tc)+mir*cir*(T - Tir) = 0
Tir = 20.3 °C + 300 g * 4.186 J/g°C * (20.3 C - 19 °C) / ( 51.9 g * 0.449 J/g°C )
Tir = 90.36 °C
Note :
- The specific heat capacity of water is assumed 1 cal/g°C = 4.186 J/g°C
- We assume no reaction between iron and water
False. harry styles all the way
