Answer:
pH = 3.3
Explanation:
Buffer solutions minimize changes in pH when quantities of acid or base are added into the mix. The typical buffer composition is a weak electrolyte (wk acid or weak base) plus the salt of the weak electrolyte. On addition of acid or base to the buffer solution, the solution chemistry functions to remove the acid or base by reacting with the components of the buffer to shift the equilibrium of the weak electrolyte left or right to remove the excess hydronium ions or hydroxide ions is a way that results in very little change in pH of the system. One should note that buffer solutions do not prevent changes in pH but minimize changes in pH. If enough acid or base is added the buffer chemistry can be destroyed.
In this problem, the weak electrolyte is HNO₂(aq) and the salt is KNO₂(aq). In equation, the buffer solution is 0.55M HNO₂ ⇄ H⁺ + 0.75M KNO₂⁻ . The potassium ion is a spectator ion and does not enter into determination of the pH of the solution. The object is to determine the hydronium ion concentration (H⁺) and apply to the expression pH = -log[H⁺].
Solution using the I.C.E. table:
HNO₂ ⇄ H⁺ + KNO₂⁻
C(i) 0.55M 0M 0.75M
ΔC -x +x +x
C(eq) 0.55M - x x 0.75M + x b/c [HNO₂] / Ka > 100, the x can be
dropped giving ...
≅0.55M x ≅0.75M
Ka = [H⁺][NO₂⁻]/[HNO₂] => [H⁺] = Ka · [HNO₂]/[NO₂⁻]
=> [H⁺] = 6.80x010⁻⁴(0.55) / (0.75) = 4.99 x 10⁻⁴M
pH = -log[H⁺] = -log(4.99 x 10⁻⁴) -(-3.3) = 3.3
Solution using the Henderson-Hasselbalch Equation:
pH = pKa + log[Base]/[Acid] = -log(Ka) + log[Base]/[Acid]
= -log(6.8 x 10⁻⁴) + log[(0.75M)/(0.55M)]
= -(-3.17) + 0.14 = 3.17 + 0.14 = 3.31 ≅ 3.3
Answer:
There are 2 hydrogen atoms, one magnesium atom, and 5 atoms in total.
Explanation:
We are given a compound in formula form. To make things easier to understand, we can first convert this to the name of the compound.
- When a compound contains one or more elements in parentheses, these are usually a <u>polyatomic ion</u>.
- Polyatomic ions are ions made up of two or more elements with a positive or negative charge over the entire ion. Commons examples of these NH₄⁺ (ammonia) and HCO₃⁻ (bicarbonate).
- You can combine metals with polyatomic ions to create commonly known compounds, such as baking soda. The chemical name for baking soda is sodium bicarbonate, so we can combine Na (sodium) with HCO₃⁻ (bicarbonate) and create sodium bicarbonate: NaHCO₃.
This compound is one magnesium atom bonded to two hydroxide ions.
- Hydroxide is the compound between one hydrogen atom and one oxygen atom. The compound overall adopts a negative charge of 1.
- If we have one hydrogen atom and one oxygen atom, the most electronegative atom is written first in chemical formulas. Therefore, the symbol for Oxygen (O) goes first.
- Then, write in the hydrogen atom directly after the O symbol: OH.
- Finally, since we have a negative charge on the ion, we need to play a negative sign as a superscript for the compound. Therefore, this becomes OH⁻.
Now, we need to determine the charge on the Magnesium atom which is determined from the amount of valence electrons the atom has.
- On a periodic table, the symbol for Magnesium is Mg and this element has 2 valence electrons.
- In order to fulfill the Octet Rule, the It is more likely to give up 2 electrons to a nonmetal than it is to gain 6, so we can safely assume that the charge is ²⁺.
- We need to use the criss-cross technique to transfer the charges between the element and the ion, so the negative 1 charge goes to the Mg, which does not appear (negative 1 or positive 1 are implied) and since the magnesium has a charge of positive 2, this is the subscript for the hydroxide ion.
- Therefore, our compound becomes Mg(OH)₂, and we have labeled this as magnesium hydroxide.
Now, to the number of atoms:
- The new charge on Mg is 1-, so there is only one atom of Mg.
- The charge is 2+ on the OH ion, so there are two atoms of H and two atoms of O.
- Two atoms of oxygen, two atoms of hydrogen, and one atom of magnesium add up to be five atoms in total.
When a radioactive isotope releases an alpha particle, the atomic number of the atom is decreased by four.
So, the correct answer is B.
Hope this helps,
Davinia.
Mechanical energy=
Kinetic energy + potential energy
Hope this helped!
