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DochEvi [55]
3 years ago
9

Silicon carbide (SiC) is an important ceramic material made by reacting sand (silicon dioxide, SiO2) with powdered carbon at a h

igh temperature. Carbon monoxide is also formed. When 100.0 kg of sand is processed, 51.4 kg of SiC is recovered. What is the percent yield of SiC from this process
Chemistry
1 answer:
makkiz [27]3 years ago
4 0

Answer:

Percent yield of SiC is 77.0%.

Explanation:

Balanced reaction: SiO_{2}+3C\rightarrow SiC+2CO

Molar mass of SiC = 40.11 g/mol

Molar mass of SiO_{2} = 60.08 g/mol

So, 100.0 kg of SiO_{2} = \frac{100.0\times 10^{3}}{60.08} moles of SiO_{2} = 1664 moles of SiO_{2}

According to balanced equation, 1 mol of SiO_{2} produces 1 mol of SiC

Therefore, 1664 moles of SiO_{2} produce 1664 moles of SiC

Mass of 1664 moles of SiC = (1664\times 40.11)g = 66743g = 66.74 kg (4 sig. fig.)

Percent yield of SiC = [(actual yield of SiC)/(theoretical yield of SiC)]\times 100%

                                 = \frac{51.4kg}{66.74kg}\times 100 %

                                 = 77.0%

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Answer:

According to their expected pKa values, the order of those acids should be:

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2- ClCH2COOH is a strong acid, but no more than the first. Medium pKa value.

3- ClCH2CH2COOH is a strong acid, but no more than the two previous acids. High pKa value.

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The pKa values are the negative logarithm of dissociation constant. It represents the relative strengths of the acids. Stronger acids show smaller pKa values and weak acids present larger pKa value. The stronger the acid, the weaker it's the conjugate base. The larger the pKa of the conjugate base, the stronger the acid. The strength of an acid is inversely related to the strength of its conjugate.

Conjugate bases are the substance that has one less proton than the parent acid. The conjugate base of the acid presented in the problem are:

ClCH2COOH -> ClCH2COO-  + H+

ClCH2CH2COOH -> ClCH2CH2COO- + H+

CH3CH2COOH -> CH3CH2COO- + H+

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ClCH2CH2COOH. The negative charge is stabilized by resonance and electron-withdrawing atom but the effect is less compared to the two acids showed previously.

CH3CH2COOH. The negative charge is stabilized by resonance and destabilized due to CH3 group. This is the weakest acid among the problem.

Stronger acids have smaller pKa values and weak acids have larger pKa values. Due to the information present in this problem, Cl2CHCOOH is the strongest acid and the lowest pKa. CH3CH2COOH is the weakest acid, so the highest pKa value.

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4- CH3CH2COOH  is the weakest acid, so the highest pKa value.

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