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Galina-37 [17]
3 years ago
8

A 115.0-g sample of oxygen was produced by heating 400.0 g of potassium chlorate.2KClO3 Right arrow. 2KCI + 3O2What is the perce

nt yield of oxygen in this chemical reaction?Use Percent yield equals StartFraction actual yield over theoretical yield EndFraction times 100..
Chemistry
1 answer:
STALIN [3.7K]3 years ago
5 0

Answer:

73.4% is the percent yield

Explanation:

2KClO₃ →  2KCl  + 3O₂

This is a decomposition reaction, where 2 moles of potassium chlorate decompose to 2 moles of potassium chloride and 3 moles of oxygen.

We determine the moles of salt: 400 g . 1. mol /122.5g= 3.26 moles of KClO₃

In the theoretical yield of the reaction we say:

2 moles of potassium chlorate can produce 3 moles of oxygen

Therefore, 3.26 moles of salt, may produce (3.26 . 3) /2 = 4.89 moles of O₂

The mass of produced oxygen is: 4.89 mol . 32 g /1mol = 156.6g

But, we have produced 115 g. Let's determine the percent yield of reaction

Percent yield = (Produced yield/Theoretical yield) . 100

(115g / 156.6g) . 100 = 73.4 %

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Determine the rate law and the value of k for the following reaction using the data provided.
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<u>Answer:</u> The rate law expression is \text{Rate}=k[NO]^2[O_2]^1 and value of 'k' is 1.727\times 10^3M^{-2}s^{-1}

<u>Explanation:</u>

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

2NO(g)+O_2(g)\rightarrow 2NO_2(g)

Rate law expression for the reaction:

\text{Rate}=k[NO]^a[O_2]^b

where,

a = order with respect to nitrogen monoxide

b = order with respect to oxygen

  • <u>Expression for rate law for first observation:</u>

8.55\times 10^{-3}=k(0.030)^a(0.0055)^b       ....(1)

  • <u>Expression for rate law for second observation:</u>

1.71\times 10^{-2}=k(0.030)^a(0.0110)^b       ....(2)

  • <u>Expression for rate law for third observation:</u>

3.42\times 10^{-2}=k(0.060)^a(0.0055)^b      ....(3)

Dividing 1 from 2, we get:

\frac{1.71\times 10^{-2}}{8.55\times 10^{-3}}=\frac{(0.030)^a(0.0110)^b}{(0.030)^a(0.0055)^b}\\\\2=2^b\\b=1

Dividing 1 from 3, we get:

\frac{3.42\times 10^{-2}}{8.55\times 10^{-3}}=\frac{(0.060)^a(0.0055)^b}{(0.030)^a(0.0055)^b}\\\\2^2=2^a\\a=2

Thus, the rate law becomes:

\text{Rate}=k[NO]^2[O_2]^1

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

8.55\times 10^{-3}=k[0.030]^2[0.0055]^1\\\\k=1.727\times 10^3M^{-2}s^{-1}

Hence, the rate law expression is \text{Rate}=k[NO]^2[O_2]^1 and value of 'k' is 1.727\times 10^3M^{-2}s^{-1}

4 0
3 years ago
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