The reaction of acid, assuming HCl and calcium carbonate always produces a gas. The reaction is as follows:
2 HCl + CaCO3 --> CaCl2 + H2CO3
H2CO3, carbonic acid, is a weak acid that is unstable in water solutions at high concentrations. As such, it decomposes:
H2CO3 --> H2O + CO2
Then,
2 HCl + CaCO3 --> CaCl2 + H2O + CO2
The total ionic equation looks as follows:
2H+(aq) + 2 Cl-(aq) + CaCO3(s) --> Ca+2(aq) + 2 Cl-(aq) + H2O(l) + CO2(g)
Clearly, Cl- is a spectator ion as it is unchanged in the reaction. The net ionic reaction looks as follows:
2 H+(aq) + CaCO3(s) --> Ca+2(aq) + H2O(l) + CO2(g)
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