Answer:
P(total) = 164 mmHg
Explanation:
Given data:
Partial pressure of helium = 77 mmHg
Partial pressure of nitrogen = 87 mmHg
Total pressure of flask = ?
Solution:
According to Dalton law of partial pressure,
The total pressure inside container is equal to the sum of partial pressures of individual gases present in container.
Mathematical expression:
P(total) = P₁ + P₂ + P₃+ ............+Pₙ
Now we will solve this problem by using this law.
P(total) = P(He) + P(N₂)
P(total) = 77 mmHg + 87 mmHg
P(total) = 164 mmHg
Answer:
Ionisation energy increases along a period but decreases down a group
Explanation:
As you go along the period, the amount of protons in the nuclear increases. This causes nuclear attraction to increase meaning the attraction between the protons and the electrons is higher. This causes the electrons to be held more tightly to the nucleus meaning they are harder to remove. As well as that, the shielding stays the same along a period since the electrons are being added to the same shell, just different orbitals. Overall this makes it harder to remove an electron as you go along a period causing the ionisation energy to increase along a period.
On the other hand when you go down a group, the atomic radius increases. This is because the electrons are added to new shells which are further away from the nucleus, this also causes shielding to increase as there are more shells. This means the outer electrons being removed are held less tightly by the protons in the nucleus meaning they are easier to remove. This means that the ionisation energy decrease down a group.
When electrons are shared equally, the result is a metallic bond.
Answer: 
Explanation:
Given
Initial mass 
half-life is 
At any time the left amount is given by
The mechanism is as suggested
1) Protonation of alcohol
2) removal of water molecule to give carbocation
3) hydride shift to give more stable carbocation [rearrangement]
4) the stability of carbocation due to resonance
5) removal of proton and formation 1-phenyl-1-propanone.
This is Pinacole pinacolone rearrangement
Thus the reaction can be depicted as
