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KatRina [158]
3 years ago
11

The reaction of hydrogen bromide(g) with chlorine(g) to form hydrogen chloride(g) and bromine(g) proceeds as follows: 2HBr(g) +

Cl2(g)2HCl(g) + Br2(g) When 23.9 g HBr(g) reacts with sufficient Cl2(g), 12.0 kJ is evolved. Calculate the value of rH for the chemical equation given.
Chemistry
1 answer:
VladimirAG [237]3 years ago
8 0

Answer:

The enthalpy of reaction per mole of HBr for this reaction = ΔrH = -40.62 kJ/mole.

Explanation:

2HBr(g) + Cl2(g) → 2HCl(g) + Br2(g)

When 23.9 g HBr(g) reacts with sufficient Cl2(g), 12.0 kJ of heat is evolved, calculate the value of ΔrH for the chemical reaction.

Note that ΔrH is the enthalpy per mole for the reaction.

Molar mass of HBr (g) = 80.91 g/mol.

Hence, 1 mole of HBr = 80.91 g

23.9 g of HBr led to the reaction giving off 12.0 kJ of heat

80.91 g of HBr will lead to the evolution of (80.91 × 12/23.9) = 40.62 kJ heat is given off.

Hence, 40.62 kJ of heat is given off per 80.91 g of HBr.

This directly translates to that 40.62 kJ of heat is given off per 1 mole of HBr

Hence, the heat given off per mole of HBr for this reaction is 40.62 kJ/mole.

But since the reaction liberates heat, it means the reaction is exothermic and the enthalpy change for the reaction (ΔHrxn) is negative.

Hence, ΔrH = -40.62 kJ/mole.

Hope this Helps!!!

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Complete Question:

A chemist prepares a solution of silver (I) perchlorate (AgCIO4) by measuring out 134.g of silver (I) perchlorate into a 50.ml volumetric flask and filling the flask to the mark with water. Calculate the concentration in mol/L of the silver (I) perchlorate solution. Round your answer to 2 significant digits.

Answer:

13 mol/L

Explanation:

The concentration in mol/L is the molarity of the solution and indicates how much moles have in 1 L of it. So, the molarity (M) is the number of moles (n) divided by the volume (V) in L:

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The number of moles is the mass (m) divided by the molar mass (MM). The molar mass of silver(I) perchlorate is 207.319 g/mol, so:

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n = 0.646 mol

So, for a volume of 50 mL (0.05 L), the concentration is:

M = 0.646/0.05

M = 12.92 mol/L

Rounded to 2 significant digits, M = 13 mol/L

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