Total internal energy change is equals to -44.83kJ
Q=-73.2kJ (negative sign indicates that heat was released by the system),
P= 50.0atm
ΔU= Q + W, FIRST LAW OF THERMODYNAMICS..........(1)
ΔV= Final volume - initial volume= 2.00 litre - 7.60litre= -5.60litre
work done by the system (w)= -PΔV
w= -(50.0×(-5.60)) atm×litre= 280atm litre
1 atm litre= 101.325J
w= 280 ×101.325 J= 28,371J
1kJ=1000J,
w=28.37KJ,
so putting in the values in equation (1)...
energy change(ΔU) = -73.2 kJ + 28.37 kJ
= - 44.83 kJ
For both of them, used the balanced equation and it’s mole ratio to convert whatever you need to into moles. See the attacked work.
1) D 5 mols
2) A 0.55 mols
Base is Ca(OH)2.
Acid is H3PO4.
First part of the salt comes from base,
second par comes from the acid.
Potassium or any other metals.