Answer:
Decrease temperature with increase in ammonium nitrate concentration.
Explanation:
The temperature changes when different masses of ammonium nitrate are dissolved in water because the ammonium nitrate takes energy from the surrounding water environment for the breaking of ionic bonds as a result the temperature of water decreases. When more concentration of ammonium nitrate is added to water, more decrease occur in temperature of water and the water becomes cold.
Answer:
0.35 V
Explanation:
(a) Standard reduction potentials
<u> E°/V</u>
Fe²⁺ + 2e- ⇌ Fe; -0.41
Cr³⁺ + 3e⁻ ⇌ Cr; -0.74
(b) Standard cell potential
<u> E°/V</u>
2Cr³⁺ + 6e⁻ ⇌ 2Cr; +0.74
<u>3Fe ⇌ 3Fe²⁺ + 6e-; </u> <u>-0.41
</u>
2Cr³⁺ + 3Fe ⇌ 2Cr + 3Fe²⁺; +0.33
3. Cell potential
2Cr³⁺(0.75 mol·L⁻¹) + 6e⁻ ⇌ 2Cr
<u>3Fe ⇌ 3Fe²⁺(0.25 mol·L⁻¹) + 6e-
</u>
2Cr³⁺(0.75 mol·L⁻¹) + 3Fe ⇌ 2Cr + 3Fe²⁺(0.25 mol·L⁻¹)
The concentrations are not 1 mol·L⁻¹, so we must use the Nernst equation
(a) Data
E° = 0.33 V
R = 8.314 J·K⁻¹mol⁻¹
T = 298 K
z = 6
F = 96 485 C/mol
(b) Calculations:
![Q = \dfrac{\text{[Fe}^{2+}]^{3}}{ \text{[Cr}^{3+}]^{2}} = \dfrac{0.25^{3}}{ 0.75^{2}} =\dfrac{0.0156}{0.562} = 0.0278\\\\E = 0.33 - \left (\dfrac{8.314 \times 298}{6 \times 96485}\right ) \ln(0.0278)\\\\=0.33 -0.00428 \times (-3.58) = 0.33 + 0.0153 = \textbf{0.35 V}\\\text{The cell potential is }\large\boxed{\textbf{0.35 V}}](https://tex.z-dn.net/?f=Q%20%3D%20%5Cdfrac%7B%5Ctext%7B%5BFe%7D%5E%7B2%2B%7D%5D%5E%7B3%7D%7D%7B%20%5Ctext%7B%5BCr%7D%5E%7B3%2B%7D%5D%5E%7B2%7D%7D%20%3D%20%5Cdfrac%7B0.25%5E%7B3%7D%7D%7B%200.75%5E%7B2%7D%7D%20%3D%5Cdfrac%7B0.0156%7D%7B0.562%7D%20%3D%200.0278%5C%5C%5C%5CE%20%3D%200.33%20-%20%5Cleft%20%28%5Cdfrac%7B8.314%20%5Ctimes%20298%7D%7B6%20%5Ctimes%2096485%7D%5Cright%20%29%20%5Cln%280.0278%29%5C%5C%5C%5C%3D0.33%20-0.00428%20%5Ctimes%20%28-3.58%29%20%3D%200.33%20%2B%200.0153%20%3D%20%5Ctextbf%7B0.35%20V%7D%5C%5C%5Ctext%7BThe%20cell%20potential%20is%20%7D%5Clarge%5Cboxed%7B%5Ctextbf%7B0.35%20V%7D%7D)
4 sig fig in that expression
The answer is 14.22 mg / (mm^2)
Answer:
case1.
The addition of acid and base leads to a change in pH of the water when adding to deionized water due to fact that acid and bases dissociated in dissolving in water. If the H+ ion increases in the water as acid addition hikes it, it will result in decreasing the pH value. The intensity of the acid also affects the dissociation of the ions.
case2
Buffers are normally formed by weak acid and its conjugate base, and adding acid to the buffer it absorbs the H+ ions so the pH will be lower and adding base or increase of OH- conjugate base resists the pH value to increase.
