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3 years ago

5

Enter a balanced equation for the complete combustion of liquid C3H7OH. Express your answer as a chemical equation. Identify all

of the phases in your answer.

1 answer:

Vlad1618 [11]3 years ago

7 0

2 C₃H₇OH (l) + 9 O₂ (g) → 6 CO₂ (g) + 8 H₂O (g)

Explanation:

To balance the chemical equation the number of atoms of each element entering the reaction have to be equal to the number of atoms of each element leaving the reaction, in order to conserve the mass.

Bellow we have the balanced chemical equation of the complete combustion of C₃H₇OH:

C₃H₇OH (l) + (9/2) O₂ (g) → 3 CO₂ (g) + 4 H₂O (g)

to have integer coefficients we multiply the reaction with 2:

2 C₃H₇OH (l) + 9 O₂ (g) → 6 CO₂ (g) + 8 H₂O (g)

where:

(l) - liquid

(g) - gaseous

Learn more about:

combustion reaction

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balancing chemical equations

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Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. Δ H°(kJ) Ca(s)→Ca(g) 1

Drupady [299]

Answer : The value of second ionization energy of Ca is 1010 kJ.

Explanation :

The formation of calcium oxide is,

$Ca(s)+\frac{1}{2}O_2(g)\overset{\Delta H_f}\rightarrow CaO(s)$

$\Delta H_f^o$ = enthalpy of formation of calcium oxide = -635 kJ

The steps involved in the born-Haber cycle for the formation of $CaO$ :

(1) Conversion of solid calcium into gaseous calcium atoms.

$Ca(s)\overset{\Delta H_s}\rightarrow Ca(g)$

$\Delta H_s$ = sublimation energy of calcium = 193 kJ

(2) Conversion of gaseous calcium atoms into gaseous calcium ions.

$Ca(g)\overset{\Delta H_I_1}\rightarrow Ca^{+1}(g)$

$\Delta H_I_1$ = first ionization energy of calcium = 590 kJ

(3) Conversion of gaseous calcium ion into gaseous calcium ions.

$Ca^{+1}(g)\overset{\Delta H_I_2}\rightarrow Ca^{+2}(g)$

$\Delta H_I_2$ = second ionization energy of calcium = ?

(4) Conversion of molecular gaseous oxygen into gaseous oxygen atoms.

$O_2(g)\overset{\Delta H_D}\rightarrow OI(g)$

$\frac{1}{2}O_2(g)\overset{\Delta H_D}\rightarrow O(g)$

$\Delta H_D$ = dissociation energy of oxygen = $\frac{498}{2}=249kJ$

(5) Conversion of gaseous oxygen atoms into gaseous oxygen ions.

$O(g)\overset{\Delta H_E_1}\rightarrow O^-(g)$

$\Delta H_E_1$ = first electron affinity energy of oxygen = -141 kJ

(6) Conversion of gaseous oxygen ion into gaseous oxygen ions.

$O^-(g)\overset{\Delta H_E_2}\rightarrow O^{2-}(g)$

$\Delta H_E_2$ = second electron affinity energy of oxygen = 878 kJ

(7) Conversion of gaseous cations and gaseous anion into solid calcium oxide.

$Ca^{2+}(g)+O^{2-}(g)\overset{\Delta H_L}\rightarrow CaO(s)$

$\Delta H_L$ = lattice energy of calcium oxide = -3414 kJ

To calculate the overall energy from the born-Haber cycle, the equation used will be:

$\Delta H_f^o=\Delta H_s+\Delta H_I_1+\Delta H_I_2+\Delta H_D+\Delta H_E_1+\Delta H_E_2+\Delta H_L$

Now put all the given values in this equation, we get:

$-635kJ=193kJ+590kJ+\Delta H_I_2+249kJ+(-141kJ)+878kJ+(-3414kJ)$

$\Delta H_I_2=1010kJ$

Therefore, the value of second ionization energy of Ca is 1010 kJ.

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