<span> NaNO3: Soluble 2. AgBr: Insoluble 3. NH4OH: Soluble 4. Ag2CO3: Insoluble 5. NH4Br: Soluble 6. BaSO4: Insoluble 7. Pb(OH)2: Insoluble 8. PbCO3: Insoluble</span>
Photochemical equivalence law
A) Since the plot 1/[AB] vs time gives straight line, the order of the reaction with respect to A is second order:
rate constant, K = slope = 5.5 x 10⁻² M⁻¹S⁻¹
b) Rate law : Rate = k[AB]²
c) half life period of the 2nd order is inversely proportional to the initial concentration of the reactants
t 1/2 =

.

t 1/2 =

d) k = 5.5 x 10⁻² M⁻¹s⁻¹
Initial concentration of AB, [A₀] = 0.250 M
concentration of AB after 75 s = [A]
k =
![\frac{1}{t} [ \frac{1}{[A]} - \frac{1}{[Ao]} ]](https://tex.z-dn.net/?f=%20%5Cfrac%7B1%7D%7Bt%7D%20%5B%20%5Cfrac%7B1%7D%7B%5BA%5D%7D%20-%20%20%5Cfrac%7B1%7D%7B%5BAo%5D%7D%20%5D)
[A] = 0.123 M
Equation: AB → A + B
concentration of AB after 75 s = 0.123 M
Amount of AB dissociated = 0.25 - 0.123 = 0.127 M
concentration of [A] produced = concentration of [B] produced = Amount of AB reacted = 0.127 M
Mass of Copper : 63.5 g
<h3>Further explanation</h3>
Given
Reaction
Cu(s)+2AgNO₃ (aq) ⇒Cu(NO₃)₂ (aq)+2Ag(s)
Required
Mass of Copper
Solution
mol of Silver nitrate :
= M x V
= 2 mol/L x 0.5 L
= 1
From the equation, mol ratio of Cu : AgNO₃ = 1 : 2, so mol Cu = 1
Mass of Cu(Ar=63.5 g/mol) :
= mol x Ar
= 1 x 63.5
= 63.5 g