How can cobalt blue glass help us to see violet and blue light?
1 answer:
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This requires familiarity with the different theories (or concepts) of acids and bases.
On the Arrhenius concept, an acid is a substance that produces an H⁺ ion in water such that the H⁺ concentration increases, and a base is a substance that produces an OH⁻ ion in water such that the OH⁻ concentration increases.
On the Brønsted–Lowry concept, an acid is a substance that donates a proton (which is basically an H⁺ ion) in a solvent, and a base is a substance that accepts a proton in a solvent.
On the Lewis concept, an acid is a substance that accepts an electron pair in a solvent, and a base is a substance that donates an electron pair in a solvent.
The concepts become progressively broader, i.e., the Arrhenius concept is the most restrictive and the Lewis concept is the least restrictive. As a corollary, an Arrhenius acid or base is also both a Brønsted–Lowry acid or base and a Lewis acid or base, respectively; a Brønsted–Lowry acid or base is not necessarily an Arrhenius acid or base, but an Arrhenius acid or base is also a Lewis acid or base, respectively. And finally, a Lewis acid or base may not necessarily be either an Arrhenius or a Brønsted–Lowry acid or base.
So, with the above concepts in mind, we can match the statements in column A with the type of acid or base in column B:
Answer:
sp³d¹ hybridization
Explanation:
Given Cl as central element with three F substrates ...
The VSEPR structure indicates 5 hybrid orbitals that contain 2 diamagnetic orbitals (non-bonded e⁻-pairs) and 3 paramagnetic orbitals (single, non-paired electron for covalent bonding with fluorine) giving a trigonal bypyrimidal parent with a T-shaped geometry.
Valence bond theory predicts the following during bonding:
Cl:[Ne]3s²3p²p²p¹3d⁰
=> [Ne]3s²p²p¹p¹d¹
=> [Ne]3(sp³d)²(sp³d)²(sp³d)¹(sp³d)¹(sp³d)¹
giving 3 ( [Cl](sp³d) - [F]2p¹ ) sigma bonds and 2 non-bonded pairs on Cl.
Note the following images:
Non-bonded electron pairs are in plane of parent geometry and Fluorides covalently bonded to central element Chloride forming the T-shaped geometry.
