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Bond [772]
3 years ago
15

Determine the specific heat of a material if a 35. Gram sample absorbed 96. Joules of energy as it was heated from 293 K to 313

K. Answer in two Sig figs and includes units.
Chemistry
1 answer:
podryga [215]3 years ago
6 0

The specific heat of a material is 0.137 J/g°C.

<u>Explanation:</u>

The specific heat formula relates the heat energy required to perform a certain reaction with the mass of the reactants, specific heat and the change in temperature during the reaction.

Q = mcΔT

Here m is the mass, Q is the heat energy required, ΔT is the change in temperature and c is the specific heat.

So, if we have to determine the specific heat of the object, then we have to determine the ratio of heat required to mass of the object with change in time, as shown below.

c = \frac{Q}{m\ \times\ delta\ T}

As mass of the object m is given as 35 g and the energy is said to be absorbed so Q = 96 J.

The temperature values given should be changed from kelvin to celsius first. So, initial temperature 293 K will become 293-273.15 = 19.85°C.

Similarly, the final temperature will be 313 - 273.15 = 39.85°C.

Then, ΔT = 39.85-19.85 = 20 °C

Then,

c = \frac{96}{35 \times 20} =\frac{96}{700}  = 0.137 J/g^{o}C

So, the specific heat of a material is 0.137 J/g°C.

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An excess of sodium carbonate, Na, CO3, in solution is added to a solution containing 17.87 g CaCl2. After performing the
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Answer:

Approximately 81.84\%.

Explanation:

Balanced equation for this reaction:

{\rm Na_{2}CO_{3}}\, (aq) + {\rm CaCl_{2}} \, (aq) \to 2\; {\rm  NaCl}\, (aq) + {\rm CaCO_{3}}\, (s).

Look up the relative atomic mass of elements in the limiting reactant, \rm CaCl_{2}, as well as those in the product of interest, \rm CaCO_{3}:

  • \rm Ca: 40.078.
  • \rm Cl: 35.45.
  • \rm C: 12.011.
  • \rm O: 15.999.

Calculate the formula mass for both the limiting reactant and the product of interest:

\begin{aligned}& M({\rm CaCl_{2}}) \\ &= (40.078 + 2 \times 35.45)\; {\rm g \cdot mol^{-1}} \\ &= 110.978\; \rm g \cdot mol^{-1}\end{aligned}.

\begin{aligned}& M({\rm CaCO_{3}}) \\ &= (40.078 + 12.011 + 3 \times 15.999)\; {\rm g \cdot mol^{-1}} \\ &= 100.086\; \rm g \cdot mol^{-1}\end{aligned}.

Calculate the quantity of the limiting reactant (\rm CaCl_{2}) available to this reaction:

\begin{aligned}n({\rm CaCl_{2}) &= \frac{m({\rm {CaCl_{2}})}}{M({\rm CaCl_{2}})} \\ &= \frac{17.87\; \rm g}{110.978\; \rm g \cdot mol^{-1}} \\ &\approx 0.161023\; \rm mol \end{aligned}.

Refer to the balanced equation for this reaction. The coefficients of the limiting reactant (\rm CaCl_{2}) and the product ({\rm CaCO_{3}}) are both 1. Thus:

\displaystyle \frac{n({\rm CaCO_{3}})}{n({\rm CaCl_{2}})} = 1.

In other words, for every 1\; \rm mol of \rm CaCl_{2} formula units that are consumed, 1\; \rm mol\! of \rm CaCO_{3} formula units would (in theory) be produced. Thus, calculate the theoretical yield of \rm CaCO_{3}\! in this experiment:

\begin{aligned} & n(\text{${\rm CaCO_{3}}$, theoretical}) \\ =\; & n({\rm CaCl_{2}}) \cdot \frac{n({\rm CaCO_{3}})}{n({\rm CaCl_{2}})} \\ \approx \; & 0.161023\; {\rm mol} \times 1 \\ =\; & 0.161023\; \rm mol\end{aligned}.

Calculate the theoretical yield of this experiment in terms of the mass of \rm CaCO_{3} expected to be produced:

\begin{aligned} & m(\text{${\rm CaCO_{3}}$, theoretical}) \\ = \; & n(\text{${\rm CaCO_{3}}$, theoretical}) \cdot M(({\rm CaCO_{3}}) \\ \approx \; & 0.161023\; {\rm mol} \times 100.086\; {\rm g \cdot mol^{-1}} \\ \approx \; & 16.1161\; \rm g \end{aligned}.

Given that the actual yield in this question (in terms of the mass of \rm CaCO_{3}) is 13.19\; \rm g, calculate the percentage yield of this experiment:

\begin{aligned} & \text{percentage yield} \\ =\; & \frac{\text{actual yield}}{\text{theoretical yield}} \times 100\% \\ \approx \; & \frac{13.19\; {\rm g}}{16.1161\; {\rm g}} \times 100\% \\ \approx \; & 81.84\%\end{aligned}.

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