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slamgirl [31]
3 years ago
11

The total volume of seawater is 1.5 x 1021L .Assume that seawater contains 3.1 percent sodium chloride by mass and that its dens

ity is 1.03 g/mL .Calculate the total mass of sodium chloride in kilograms and in tons (1ton =2000lb; 1lb =453.6 g).
Chemistry
1 answer:
son4ous [18]3 years ago
5 0

Answer:

Mass in kg = 4.7*10^19 kg

Mass in tons = 5.2*10^16 tons

Explanation:

<u>Given:</u>

Total volume of sea water = 1.5*10^21 L

Mass % NaCl in seawater = 3.1%

Density of seawater = 1.03 g/ml

<u>To determine:</u>

Total mass of NaCl in kg and in tons

<u>Calculation:</u>

Unit conversion:

1 L = 1000 ml

The volume of seawater in ml is:

=\frac{1.5*10^{21}L*1000ml }{1L} =1.5*10^{24} ml

Mass\ seawater = Density*volume = 1.03g/ml*1.5*10^{24} ml=1.5*10^{24}g

Mass\ NaCl\ in\ seawater = \frac{3.1}{100}*1.5*10^{24}  g=4.7*10^{22} g

To convert mass from g to Kg:

1000 g = 1 kg

Mass\ seawater(kg) = \frac{4.7*10^{22}g*1kg }{1000g} =4.7*10^{19} kg

To convert mass from g to tons:

1 ton = 9.072*10^6 g

Mass\ seawater(tons) = \frac{4.7*10^{22}g*1ton }{9.072*10^{6}g } =5.2*10^{16} tons

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A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc
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Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

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2 years ago
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