Answer:
Based on compounds given, NO reaction occurs
Explanation
The compounds should exchange ions to generate a driving force that pulls the reaction to completion. => Example ...
The Molecular Equation is ...
NH₄Cl(aq) + AgNO₃(aq) => NH₄NO₃(aq) + AgCl(s)
Silver chloride forms in this reaction as a solid precipitate because of its low solubility and is the 'Driving Force' of the reaction. Driving Force is a more stable compound than any on the reactant side and when formed leaves the reaction system as a solid ppt, liquid weak electrolyte (i.e., weak acid or weak base) or a gas decomposition product of a weak electrolyte.
The Ionic Equation is ...
NH₄⁺(aq) + Cl⁻(aq) + Ag⁺(aq) + NO₃⁻(aq) => NH₄⁺(aq) + NO₃⁻(aq) + AgCl(s)
This shows all ions from reaction plus the Driving Force of the reaction.
The Net Ionic Equation is ...
Ag⁺(aq) + Cl⁻(aq) => AgCl(s)
The Net Ionic Equation shows only those ions undergoing reaction. The NH₄⁺ and NO₃⁻ ions are 'Spectator Ions' and do not react.
Attached is a reference sheet for determining the Driving Force of a Metathesis Double Replacement Reaction. Suggest reviewing acid-base theories and the products of decomposition type reactions.
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>
The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>
Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
Answer:
See the attached image
Explanation:
The first step is the production of the <u>carboanion</u> in the compound. We will get the <u>negative charge</u> on the methyl group and the <u>positive charge</u> in the Li atom.
Then the carboanion can <u>attack the acetone</u>. The double bond of the oxo group would <u>delocalized</u> upon the oxygen, generating a positive charge in the carbon that can be attacked by the carboanion formaiting a <u>new C-C bond</u>.
Effects of changes in volume in a reversible reaction in a chemical equilibrium can be predicted using Le Chatelier's Principle. I think this might be the answer, I hope it helps.