D. She is not right, because there will be more successful collisions
between reactants in the concentrated solutions.
Answer : The number of moles of gas present in container are 1.697 mole.
Explanation :
Using ideal gas equation,

where,
P = pressure of gas = 74 mmHg = 0.097 atm
conversion used : (1 atm = 760 mmHg)
V = volume of gas = 500.0 L
T = temperature of gas = 
n = number of moles of gas = ?
R = gas constant = 0.0821 L.atm/mole.K
Now put all the given values in the ideal gas equation, we get the number of moles of gas in the container.


Therefore, the number of moles of gas present in container are 1.697 mole.
I think the answer you have selected is right, I'm not sure tho
This is an incomplete question, here is a complete question.
The conversion of cyclopropane to propene occurs with a first-order rate constant of 2.42 × 10⁻² hr⁻¹. How long will it take for the concentration of cyclopropane to decrease from an initial concentration 0.080 mol/L to 0.053 mol/L?
Answer : The time taken will be, 17.0 hr
Explanation :
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = 
t = time passed by the sample = ?
a = initial concentration of the reactant = 0.080 M
a - x = concentration left = 0.053 M
Now put all the given values in above equation, we get


Therefore, the time taken will be, 17.0 hr