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jasenka [17]
3 years ago
14

g To what volume (in mL) should 5.07 mL of an 6.82 M acetic acid solution be diluted in order to obtain a final solution that is

0.49 M
Chemistry
1 answer:
denis-greek [22]3 years ago
7 0

Answer:

The volume of the solution must be increased to 71.429 millimeters by adding 66.359 millimeters of solute to reduce molarity from 6.82 M to 0.49 M.

Explanation:

The molarity is a unit used for solution that is equivalent to the amount of moles of solute per unit volume of solution. That is:

M = \frac{n_{st}}{V_{sol}}

Where:

n_{st} - Amount of moles of solute, measured in moles.

V_{sol} - Volume of the solution, measured in liters.

To reduce the molarity of the solution, more millimeters of solvent should be added. Firstly, the amount of moles of acetic acid inside the 6.82 M solution needs to be determined (M_{o} = 6.82\,M and V_{sol} = 5.07\times 10^{-3}\,L):

n_{st} = M_{o}\cdot V_{sol}

n_{st} = (6.82\,M)\cdot (5.07\times 10^{-3}\,L)

n_{st} = 0.035\,mol

Now, the resulting volume of solution after diluting the acetic acid solution is: (M_{f} = 0.49\,M and n_{st} = 0.035\,mol):

V_{sol} = \frac{n_{st}}{M_{f}}

V_{sol} = \frac{0.035\,mol}{0.49\,M}

V_{sol} = 71.429\times 10^{-3}\,L

V_{sol} = 71.429\,mL (1 L = 1000 mL)

The amount of solvent needed to dilute the solution is:

\Delta V_{sol} = 71.429\times 10^{-3}\,L - 5.07\times 10^{-3}\,L

\Delta V_{sol} = 66.359 \times 10^{-3}\,L

\Delta V_{sol} = 66.359\,mL (1 L = 1000 mL)

The volume of the solution must be increased to 71.429 millimeters by adding 66.359 millimeters of solute to reduce molarity from 6.82 M to 0.49 M.

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<u>Answer:</u> Pairs are:  (a) and (d), (b) and (f), (c) and (e)

<u>Explanation:</u>

In a periodic table, elements are arranged in 18 vertical columns known as groups and 7 horizontal rows known as periods.

Elements arranged in a group show similar chemical properties because of the presence of same number of valence electrons.

Valence electrons are defined as the electrons which are present in the outermost shell of an atom. Outermost shell has the highest value of 'n' that is principal quantum number.

For the given options:

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The given electronic configuration is:  1s^22s^22p^63s^2

The number of valence electrons in the given configuration are 2

  • <u>For b:</u>

The given electronic configuration is:  1s^22s^22p^63s^3

The number of valence electrons in the given configuration are [2 + 3] = 5

  • <u>For c:</u>

The given electronic configuration is:  1s^22s^22p^63s^23p^64s^23d^{10}4p^6

The number of valence electrons in the given configuration are [2 + 6] = 8

  • <u>For d:</u>

The given electronic configuration is:  1s^22s^2

The number of valence electrons in the given configuration are 2

  • <u>For e:</u>

The given electronic configuration is:  1s^22s^22p^6

The number of valence electrons in the given configuration are [2 + 6] = 8

  • <u>For f:</u>

The given electronic configuration is:  1s^22s^22p^63s^23p^3

The number of valence electrons in the given configuration are [2 + 3] = 5

Electronic configuration of (a) and (d) will form a pair, (b) and (f) will form a pair, (c) and (e) will form a pair and will have similar chemical properties.

Hence, the pairs are:  (a) and (d), (b) and (f), (c) and (e)

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<u>Answer:</u> The correct answer is Option B.

<u>Explanation:</u>

To calculate the molarity of solution, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}     .......(1)

  • <u>For A:</u>

Molarity of calcium phosphate solution = 0.100 M

Volume of solution = 2.00 L

Putting values in equation 1, we get:

0.100M=\frac{\text{Moles of }Ca_3(PO_4)_2}{2.00}\\\\\text{Moles of }Ca_3(PO_4)_2=(0.100mol/L\times 2.00L)=0.200mol

Moles of calcium phosphate = 0.200 moles

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1 mole of calcium phosphate contains 3 moles of calcium atoms, 2 moles of phosphate atoms and 8 moles of oxygen atoms.

So, 0.200 moles of calcium phosphate will contain = (8\times 0.200)=1.6 moles of oxygen atoms.

Moles of oxygen atoms = 1.6 moles

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Putting values in equation 1, we get:

0.100M=\frac{\text{Moles of }Ca_3(PO_4)_2}{1.00}\\\\\text{Moles of }Ca_3(PO_4)_2=(0.100mol/L\times 1.00L)=0.100mol

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Molarity of calcium phosphate solution = 0.100 M

Volume of solution = 5.00 L

Putting values in equation 1, we get:

0.100M=\frac{\text{Moles of }Ca_3(PO_4)_2}{5.00}\\\\\text{Moles of }Ca_3(PO_4)_2=(0.100mol/L\times 5.00L)=0.500mol

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According to mole concept:

1 mole of a compound contains 6.022\times 10^{23} number of atoms

Number of phosphorus atoms in 0.500 moles of calcium phosphate will be = (1.00\times 6.022\times 10^{23})=6.022\times 10^{23}

  • <u>For E:</u>

1 mole of calcium phosphate contains 3 moles of calcium ions and 2 moles of phosphate ions.

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Explanation:

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