When ketone is reacted with phosphorous pentachloride, chlorination takes place at the carbonyl carbon with substitution of the oxygen atom to give a geminal dichloride (with 2 Cl atoms on same carbon) according to the following equation:
so we can say that acetone is converted into 2,2-dichloropropane by action of PCl₅
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C—stems and leaves growing upward?
C. Include changes that alter the identity of a substance.
Option 2, Br. I'll go over why all other three options are incorrect.
Option 1 - Krypton is a Noble gas, and so it doesn't need to accept electrons since it has an octet.
Option 3 and 4 - Both Calcium and Barium are alkaline earth metals, and give away electrons, since they only have 2.
-T.B.