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lubasha [3.4K]
3 years ago
5

Electrophiles for the electrophilic aromatic substitution reactions have to be very strong to react with the stable aromatic rin

gs. A nitronium ion is needed for nitration of aromatic rings. Complete the mechanism of the formation of the nitronium ion from concentrated nitric acid in concentrated sulfuric acid.

Chemistry
1 answer:
Leokris [45]3 years ago
3 0

Answer: The nitronium ion is a strong electrophile

Explanation:

The detailed mechanism of the reaction is shown in the images attached. The flow of electrons has been shown with arrows. HNO3 is first protonated by H2SO4 this protonated specie H2NO3+ now forms H2O and NO2+.

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Why can’t there be a temperature lower than absolute zero
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Phosphorus trichloride, PCl₃ is a liquid at room temperature.
Simora [160]

Answer:

Phosphorus trichloride, PCl₃ undergoes change in bonding and molecular force of attraction, causing it to be liquid at room temperature.

Explanation:

Unlike other chlorides of Period 3 elements, Phosphorus trichloride, PCl₃ changes the structure of its molecular bonding from ionic to covalent bonds as it transitions to fluids (liquids or gases). The PCl₃ molecule also has the weak Van der Waals dispersion and dipole-dipole attraction, making it a fuming liquid at room temperature,  with no electrical conductivity.

4 0
3 years ago
A possible mechanism for the gas phase reaction of NO and H2 is as follows: Step 1 2NO N2O2 Step 2 N2O2 + H2 N2O + H2O Step 3 N2
mel-nik [20]

Answer: Option (d) is the correct answer.

Explanation:

Steps involved for the given reaction will be as follows.

Step 1: 2NO \Leftrightarrow N_{2}O_{2}    (fast)

Rate expression for step 1 is as follows.

               Rate = k [NO]^{2}

Step 2: N_{2}O_{2} + H_{2} \rightarrow N_{2}O + H_{2}O

This step 2 is a slow step. Hence, it is a rate determining step.

Step 3. N_{2}O + H_{2} \rightarrow N_{2} + H_{2}O    (fast)

Here, N_{2}O_{2} is intermediate in nature.

All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.

Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.

4 0
3 years ago
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