If a volcano epulses massive amounts of dust into the atmosphere, those two things will/can happen.
The events will last until the dust lays down on the earth.
A clear cloudless day-time sky is blue because molecules in the air scatter blue light from the sun more than they scatter red light. When we look towards the sun at sunset, we see red and orange colours because the blue light has been scattered out and away from the line of sight.
I would say that this is the first law of thermodynamics.