Answer:
PART A: The LDF occurs between all molecules. Dispersion forces result from shifting electron clouds, which cause weak, temporary dipole.
PART B: Dipole dipole operates only between polar molecules. This is when two polar molecules get near each other and the positively charged portion of the molecule is attracted to the negatively charged portion of another molecule.
PART C: Dipole dipole and in some cases hydrogen bonding operate between the hydrogen atom of a polar bond and a nearby small electronegative atom. Only if the atom bonded to it were F, O or N it would be hydrogen bonding. Otherwise it is dipole dipole.
Answer: A) This reaction will be spontaneous only at high temperatures
Explanation:
= +ve, reaction is non spontaneous
= -ve, reaction is spontaneous
= 0, reaction is in equilibrium
Using Gibbs Helmholtz equation:
Given :
Thus the value of
is negative and spontaneous when temperature is high.
Independent Variable: a variable that you can change in an experiment
Dependent Variable: something that changes as you change the independent variable
control variable: something that is not changed throughout the experiment
Answer:
ΔS° = -268.13 J/K
Explanation:
Let's consider the following balanced equation.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
We can calculate the standard entropy change of a reaction (ΔS°) using the following expression:
ΔS° = ∑np.Sp° - ∑nr.Sr°
where,
ni are the moles of reactants and products
Si are the standard molar entropies of reactants and products
ΔS° = [2 mol × S°(HNO₃(l)) + 1 mol × S°(NO(g))] - [3 mol × S°(NO₂(g)) + 1 mol × S°(H₂O(l))]
ΔS° = [2 mol × 155.6 J/K.mol + 1 mol × 210.76 J/K.mol] - [3 mol × 240.06 J/K.mol + 1 mol × 69.91 J/k.mol]
ΔS° = -268.13 J/K
Energy levels are considered orbitals.